Оne of the possible ways to improve the properties of building materials is to modify the processes of structure formation, which can be realized through the use of crystalline primers. In this regard, it is urgent to study the effect of artificial calcium hydrosilicates on hardening processes, as well as the properties of non-autoclave silicate materials based on non-traditional aluminosilicate raw materials. Studies have shown that the addition of artificial calcium hydrosilicates (CSH) in an amount of 1-1.5 wt. %, when the content in the mixture of CaO is less than 10 wt. %, effectively increases the strength parameters of products at all stages of heat and moisture treatment from 8 to 16%. The most intense increase in strength is observed during the heat-moisture treatment (TBO) from 3 to 6 hours and is at least 13%, while in samples without the addition of artificial calcium hydrosilicates, the strength increase is 6%. The addition of artificial calcium hydrosilicates intensifies the processes of structure formation, which ensures an increase in crystalline matter, and, due to the fibrous structure, acts as a fiber, which contributes to the nano-reinforcement of the cementing substance formed from neoplasms in the CaO-SiO2(Al2O3)-H2O system based on clay rocks and calcium oxide. Due to the accelerated set of strength, it is possible to reduce the duration of isothermal exposure while maintaining the necessary performance characteristics.