ADSORPTION OF SPINDLE OIL BY NATIVE AND THERMAL MODIFIED CHESTNUT TREE WASTE

https://doi.org/10.34031/2618-7183-2018-1-1-4-11
Adsorption is a widespread and effective way of treating sewage containing petroleum products. To implement this method, one of the best sorbents is activated carbon. However, sorbents based on activated coals are of high cost and require further regeneration, which significantly increases the cost of water treatment. In addition, during the regeneration of such sorption materials secondary toxic waste is formed, which also create environmental problems. Therefore, the development of new efficient and inexpensive sorption materials, especially on the base of a variety of wastes, is an urgent task.
For research, we used tree waste of the genus of horse chestnut (Latin Aésculus hippocastanum L.). Horse chestnut is widespread in the midland of the Russian Federation, CIS countries, Southern Europe. According to municipal services about 5.000 chestnut trees grow on the territory of a city with a population of about 400.000 people and tree waste of the trees covering streets and square every year. Tree waste is nowhere used and removed to landfills.
Extraction of I-20A spindle oil from model emulsions by native and thermal modified chestnut tree waste as a sorption material in industry was carried out because this oil is a widely used petroleum product. The physicochemical properties of tree waste, such as bulk density, humidity, ash content, pH of aqueous extract, specific surface area are studied.
Before extraction, the chestnut tree waste was ground to a size of 3-5 mm. Thermal treatment was carried out in a drying cabinet of the type SNOL and muffle furnace in the temperature range 100-500 C. It is established that during the thermal treatment the specific surface area of the sorption material increases from 2.6 to 27.9 m2/ g. The surface of micro relief structure changes in the direction of increasing roughness and defectiveness; sorption material acquires hydrophobic properties. The recommended thermal treatment temperature is 200 C. The efficiency of cleaning model emulsions is 91%.
1. Shaikhiev I.G., Fazullin D.D., Mavrin G.V. Modified PTFE-PANI membranes for the recovery of oil products from aqueous oil emulsions. Petroleum chemistry. 2017. 57 (2). P. 165 – 171.
2. Yu L., Han M., He F. A review of treating oily wastewater. Arabian Journal of Chemistry. 2017. 10. P. 1913 – 1922.
3. Karagodina M.N., Mishta V.P., Shajhiev I.G. Osobennosti ochistki stochnyh vod ot nefterpoduktov. Vestnik Kazanskogo tehnologicheskogo universiteta. 2015. 18(5). P. 255 – 257. (rus.)
4. Fazullin D.D., Mavrin G.V., Shaikhiev I.G., Fedotova A.V., Dryakhlov V.O., Nizameyev I.R. Purification of wastewater, containing petroleum products, using polysulfo-namide membranes, treated with high-frequency plasma in argon and nitrogen. Journal of Fundamental and Applied Sciences. 2017. 9 (1S). P. 1569 – 1580.
5. Galimova R.Z., Shajhiev I.G., Grechina A.S. Ochistka model'nyh stochnyh vod, soderzhashhih fenol i formal'degid, othodami valjal'no-vojlochnogo proizvodstva v rezhime dinamicheskoj adsorbcii. Vestnik Kazanskogo tehnologicheskogo universiteta. 2017. 20 (21). P. 116 – 118. (rus.)
6. Wang B., Shui Y., Ren H., He M. Research of combined adsorption-coagulation process in treating petroleum refinery effluent. Environmental Technology (United Kingdom). 2017. 38 (4). P. 456 – 466.
7. Starostina I.V., Stolyarov D.V., Kosukhin M.M. Carbonic and mineral adsorbent, produced of a slurry withdrawal of oil-extracting production. Solid State Phenomena. 2017. 265. P. 319 – 324.
8. Sabir S. Approach of cost-effective adsorbents for oil removal from oily water. Critical Reviews in Environmental Science and Technology. 2015. 45 (17). P. 1916 – 1945.
9. Smolova I.N., Ahmadieva A.A., Garan'kov I.N. Adsorbcionnaja ochistka stochnyh vod ot nefteproduktov na prirodnyh sorbenta. Aktual'nye voprosy sovremennoj nauki: sb. nauchn. ctatej ctudencheskoj mezhdunarodnoj nauchn.-prakt. zaochnoj konf. (Ufa, 15 aprelja, 2016g.), Ufa: UGUJeS, 2016. P. 142 – 145. (rus.)
10. Galimova R.Z, Shajhiev I.G., Almazova G.A., Sverguzova S.V. Issledovanie kinetiki processov adsorbcii fenola othodami valjal'no-vojlochnogo proizvodstva. Vestnik BGTU im. V.G. Shuhova. 2016. 10. P. 179 – 184. (rus.)
11. Blagadyreva A. M. Ochistka stochnyh vod ot nefteproduktov othodami saharnoj promyshlennosti: avtoref. dis. … kand. tehn. nauk. Belgorod, 2009. 20 p. (rus.)
12. Sverguzova S.V., Sapronova Zh.A., Starostina I.V. Disposal of synthetic surfactants-containing wastewater treatment sludge in the ceramic brick production. Procedia Engineering. 2016. 150. P. 1610 – 1616.
13. Sakalova G.V., Sverguzova S.V., Mal'ovanyj M.S. Jeffektivnost' ochistki stochnyh vod gal'vanicheskogo proizvodstva adsorbcionnym metodom. Vestnik BGTU im. V.G. Shuhova. 2014. 4. P. 153 – 156.
14. Cherpakov V.V. O bakterial'nom porazhenii pseudomonas syringae pv. aesculi konskogo kashtana v Rossijskoj Federacii. Aktual'nye problemy lesnogo kompleksa. 2013. 37. P. 70 – 77. (rus.)
15. Aref'ev Ju.F., Mamedov M.M. Konskij kashatan (Aesculus hippocastanum L.) v uslovijah bol'shih gorodov central'nogo Chernozem'ja RF: Mezhdunar. nauchn-prakt. konf. «Plodovodstvo, semenovodstvo, introdukcija drevesnyh rastenij» (Krasnojarsk, 20-21 sentjabrja, 2006g.), Krasnojarsk: SibGTU, 2006. P. 29 – 32. (rus.)
16. Aref'ev Ju.F., Mamedov M.M. O zashhite kashtana (Aesculus hippocastanum L.) v gorodskih nasazhdenijah. Ohrana okruzhajushhej sredy na territorii municipal'nyh obrazovanij: mater. II Mezhregion. nauch.-prakt. konf. (Voronezh, 30 maja, 2006g.), Voronezh: Krivichi, 2006. P.158 – 164. (rus.)
17. Shajmardanova A.Sh. Ochistka vod ot ionov zheleza modificirovannymi sorbcionnymi materialami na osnove listovogo opada: avtoref. dis. … kand. tehn. nauk. Kazan', 2017. 16 p. (rus.)
18. Shutov I.V., Ankudinov V.E., Krivilev M.D. Issledovanie poristosti poroshka oksida aljuminija metodom gazlvlj polimolekuljarnoj nizkotemperaturnoj adsorbcii. Vestnik UdGU. 2014. 3. P. 42 – 47. (rus.)
19. Sablina T.Ju., Sevost'janova I.N., Mel'nikova A.G. Udel'naja poverhnost' ul'tradispersnyh poroshkov keramiki, poluchennyh metodom plazmohimicheskogo sinteza. Ogneupory i tehnicheskaja keramika. 2007. 1. P. 11 – 13. (rus.)
20. Fetisov R.O. Sorbcionnaja ochistka stochnyh vod ot SPAV othodom proizvodstva saharnoj promyshlennosti – saturacionnym osadkom: avtoref. kand. tehn. nauk. Belgorod, 2015. 19 p. (rus.)
21. Urazaev V. Gidrofil'nost' i gidrofobnost'. Tehnologija v jelektronnoj promyshlennosti. 2006. 3. P. 33 – 36. (rus.)
22. Sverguzova S.V., Svjatchenko A.V. Ispol'zovanie pyli jelektrodugovyh staleplavil'nyh pechej dlja ochistki model'nyh stochnyh vod proizvodstva soevogo moloka. Innovacionnye puti modernizacii bazovyh otraslej promyshlennosti, jenergo- i resursosberezhenie, ohrana okruzhajushhej prirodnoj sredy: sb. nauchnyh trudov VI Mezhdunar. nauchn.-prakt. konf. Molodyh uchenyh i specialistov (Har'kov, 22-23 marta 2017 g.), Har'kov: GP «UkrNTC «Jenergostal'», 2017. P. 284 – 287. (rus.)
23. Sverguzova S.V., Sapronova Zh.A., Svjatchenko A.V. Ispol'zovanie listovogo opada kashtanov dlja izvlechenija ionov nikelja iz rastvorov. Jenergo- i resursosberegajushhie jekologicheskie chistye himiko-tehnologicheskie processy zashhity okruzhajushhej sredy: sb. dokl. III Mezhdunar. nauch.-tehn. konf. (Belgorod, 14-15 nojab., 2017), Belgorod: BGTU im. V.G. Shuhova, 2017. P. 84 – 89. (rus.)
Sverguzova S.V., Sapronova Zh.A., Svyatchenko A.V., Tom Otiti Adsorption of spindle oil by native and thermal modified chestnut tree waste. Construction Materials and Products. 2018. 1 (1). P. 4 – 11. https://doi.org/10.34031/2618-7183-2018-1-1-4-11