Русский
English
Wear and tear of technical equipment elements is a serious problem that negatively affects the productivity of production processes. The work analyzed the strength of cohesive and adhesive bonds of wear-resistant coatings obtained by detonation gas-dynamic spraying method based on a self-fluxing alloy, depending on the introduction of B4C particles into the composite composition. The chemical composition of the cohesive bonds of the resulting coatings and the effect of boron-containing elements on their strength were analyzed. The method of transverse scratching of transverse sections of thick coatings is a qualitative assessment of adhesive and cohesive properties and helps to determine the mechanisms of their destruction. The purpose of the work is to study the effect of the introduction of B4C particles on the adhesive and cohesive properties of coatings obtained by detonation gas-dynamic spraying based on self-fluxing NiCrBSi alloy. Methods for studying coating samples obtained by detonation gas-thermal method: scanning electron microscopy, energy dispersive analysis, optical metallographic microscopy, scratch testing. Previously, wear-resistant coatings based on self-fluxing NiCrBSi-B4C alloy have proven their effectiveness as protective coatings for centrifugal beet cutter knives. This study substantiates the feasibility of obtaining a composite based on such coatings with the introduction of boron carbide to improve its strength characteristics.
[1] Sirota V.V., Zaitsev S.V., Prokhorenkov D.S., Limarenko M.V., Skiba A.A., Churikov A.S., Dan’shin A.L. Detonation Application of a Hard Composite Coating to Cutters for Centrifugal Beet Shredders. Russian Engineering Research. 2023. 43 (9). P. 1142 – 1145.https://doi.org/10.3103/S1068798X23090216
[2] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979.
[3] Fenker M., Balzer M., Jehn H.A., Kappl H., Lee J.J., Lee K.H., Park H.S. Improvement of the corrosion resistance of hard wear resistant coatings by intermediate plasma etching or multilayered structure. Surface and Coatings Technology. 2002. 150 (1). P. 101 – 106. DOI: https://doi.org/10.1016/S0257-8972(01)01506-7
[4] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979. DOI: https://doi.org/10.1080/10402004.2014.927548
[5] He D., Shang L., Lu Z., Zhang G., Wang L., Xue Q. Tailoring the mechanical and tribological properties of B4C/aC coatings by controlling the boron carbide content. Surface and Coatings Technology. 2017. 329. P. 11 – 18. DOI: https://doi.org/10.1016/j.surfcoat.2017.09.017
[6] Burnett P.J., Rickerby D.S. The mechanical properties of wear-resistant coatings: II: Experimental studies and interpretation of hardness. Thin solid films. 1987. 148 (1). P. 51 – 65. DOI: https://doi.org/10.1016/0040-6090(87)90120-9
[7] Gu Y., Xia K., Wu D., Mou J., Zheng S. Technical characteristics and wear-resistant mechanism of nano coatings: a review. Coatings. 2020. 10 (3). P. 233. DOI: https://doi.org/10.3390/coatings10030233
[8] Yang B.Q., Zhang K., Chen G. N., Luo G.X., Xiao J.H. Measurement of fracture toughness and interfacial shear strength of hard and brittle Cr coating on ductile steel substrate. Surface engineering. 2008. 24(5). P. 332 – 336. DOI: https://doi.org/10.1179/174329408X282587
[9] Lima M.M., Godoy C., Modenesi P.J., Avelar-Batista J.C., Davison A., Matthews A. Coating fracture toughness determined by Vickers indentation: an important parameter in cavitation erosion resistance of WC–Co thermally sprayed coatings. Surface and Coatings Technology. 2004. 177. P. 489 – 496. DOI: https://doi.org/10.1016/S0257-8972(03)00917-4
[10] Tkadletz M., Schalk N., Daniel R., Keckes J., Czettl C., Mitterer C. Advanced characterization methods for wear resistant hard coatings: a review on recent progress. Surface and Coatings Technology. 2016. 285. P. 31 – 46. DOI: https://doi.org/10.1016/j.surfcoat.2015.11.016
[11] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979. DOI: https://doi.org/10.1080/10402004.2014.927548
[12] Dorozhkin N. N., Kashitsyn L. P. Physicomechanical characteristics of wear resistant coatings. Soviet Powder Metallurgy and Metal Ceramics. 1974. 13. P. 220 – 223. DOI: https://doi.org/10.1007/BF00790640
[13] Harfouche M.M., Alidokht S.A., Islas Encalada A., Mungala V.N., Chromik R. R., Moreau C., Makowiec M.E. Scratch Adhesion Testing of Thick HVOF Thermal Sprayed Coatings. Journal of Thermal Spray Technology. 2024. 33 (4). P. 1158 – 1166. DOI: https://doi.org/10.1007/s11666-024-01741-3
[14] Das B., Nath A., Bandyopadhyay P. P. Scratch resistance and damage mechanism of laser remelted thermally sprayed ceramic coating. Surface and Coatings Technology. 2019. 364. P. 157 – 169. DOI: https://doi.org/10.1016/j.surfcoat.2019.02.078
[15] Harfouche M.M., Alidokht S.A., Islas Encalada A., Mungala V.N., Chromik R.R., Moreau C., Makowiec M.E. Scratch Adhesion Testing of Thick HVOF Thermal Sprayed Coatings. Journal of Thermal Spray Technology. 2024. 33 (4). P. 1158 – 1166. DOI: https://doi.org/10.1007/s11666-024-01741-3
[16] Vencl A., Arostegui S., Favaro G., Zivic F., Mrdak M., Mitrović S., Popovic V. Evaluation of adhesion/cohesion bond strength of the thick plasma spray coatings by scratch testing on coatings cross-sections. Tribology International. 2011. 44 (11). P. 1281 – 1288.
[17] Bayatlı A., Şahin E. F., Kocabaş M. Effect of boron carbide reinforcement on surface properties of electroless Ni–B and Ni–B–W coatings. Materials Chemistry and Physics. 2023. 305. P. 127899. DOI: https://doi.org/10.1016/j.matchemphys.2023.127899
[18] He D., Shang L., Lu Z., Zhang G., Wang L., Xue Q. Tailoring the mechanical and tribological properties of B4C/aC coatings by controlling the boron carbide content. Surface and Coatings Technology. 2017. 329. P. 11 – 18. DOI: https://doi.org/10.1016/j.surfcoat.2017.09.017
[19] Ramesh B., Elsheikh A.H., Satishkumar S., Shaik A.M., Djuansjah J., Ahmadein M., Alsaleh N.A. The Influence of boron carbide on the mechanical properties and bonding strength of B4C/Nickel 63 coatings of brake disc. Coatings. 2022. 12 (5). P. 663. DOI: https://doi.org/10.3390/coatings12050663
[20] Waichman S., Froim S., Zukerman I., Buzaglo M., Chachashvili M., Barzilai S. Magnetron sputtering of boron carbide coating on aluminum substrate – Experimental considerations for enhancing adhesion. Surfaces and Interfaces. 2023. 38. P. 102772. DOI: https://doi.org/10.1016/j.surfin.2023.102772
[21] Sirota V., Zaitsev S., Limarenko M., Prokhorenkov D., Lebedev M., Churikov A., Dan'shin A. Preparation of coatings with high infrared emissivity. Metal Working and Material Science. 2024. 26(2). P. 23 – 37. DOI: 10.17212/1994-6309-2024-26.2-23-37
[2] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979.
[3] Fenker M., Balzer M., Jehn H.A., Kappl H., Lee J.J., Lee K.H., Park H.S. Improvement of the corrosion resistance of hard wear resistant coatings by intermediate plasma etching or multilayered structure. Surface and Coatings Technology. 2002. 150 (1). P. 101 – 106. DOI: https://doi.org/10.1016/S0257-8972(01)01506-7
[4] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979. DOI: https://doi.org/10.1080/10402004.2014.927548
[5] He D., Shang L., Lu Z., Zhang G., Wang L., Xue Q. Tailoring the mechanical and tribological properties of B4C/aC coatings by controlling the boron carbide content. Surface and Coatings Technology. 2017. 329. P. 11 – 18. DOI: https://doi.org/10.1016/j.surfcoat.2017.09.017
[6] Burnett P.J., Rickerby D.S. The mechanical properties of wear-resistant coatings: II: Experimental studies and interpretation of hardness. Thin solid films. 1987. 148 (1). P. 51 – 65. DOI: https://doi.org/10.1016/0040-6090(87)90120-9
[7] Gu Y., Xia K., Wu D., Mou J., Zheng S. Technical characteristics and wear-resistant mechanism of nano coatings: a review. Coatings. 2020. 10 (3). P. 233. DOI: https://doi.org/10.3390/coatings10030233
[8] Yang B.Q., Zhang K., Chen G. N., Luo G.X., Xiao J.H. Measurement of fracture toughness and interfacial shear strength of hard and brittle Cr coating on ductile steel substrate. Surface engineering. 2008. 24(5). P. 332 – 336. DOI: https://doi.org/10.1179/174329408X282587
[9] Lima M.M., Godoy C., Modenesi P.J., Avelar-Batista J.C., Davison A., Matthews A. Coating fracture toughness determined by Vickers indentation: an important parameter in cavitation erosion resistance of WC–Co thermally sprayed coatings. Surface and Coatings Technology. 2004. 177. P. 489 – 496. DOI: https://doi.org/10.1016/S0257-8972(03)00917-4
[10] Tkadletz M., Schalk N., Daniel R., Keckes J., Czettl C., Mitterer C. Advanced characterization methods for wear resistant hard coatings: a review on recent progress. Surface and Coatings Technology. 2016. 285. P. 31 – 46. DOI: https://doi.org/10.1016/j.surfcoat.2015.11.016
[11] Simunovic K., Saric T., Simunovic G. Different approaches to the investigation and testing of the Ni-based self-fluxing alloy coatings – A review. Part 1: General facts, wear and corrosion investigations. Tribology Transactions. 2014. 57 (6). P. 955 – 979. DOI: https://doi.org/10.1080/10402004.2014.927548
[12] Dorozhkin N. N., Kashitsyn L. P. Physicomechanical characteristics of wear resistant coatings. Soviet Powder Metallurgy and Metal Ceramics. 1974. 13. P. 220 – 223. DOI: https://doi.org/10.1007/BF00790640
[13] Harfouche M.M., Alidokht S.A., Islas Encalada A., Mungala V.N., Chromik R. R., Moreau C., Makowiec M.E. Scratch Adhesion Testing of Thick HVOF Thermal Sprayed Coatings. Journal of Thermal Spray Technology. 2024. 33 (4). P. 1158 – 1166. DOI: https://doi.org/10.1007/s11666-024-01741-3
[14] Das B., Nath A., Bandyopadhyay P. P. Scratch resistance and damage mechanism of laser remelted thermally sprayed ceramic coating. Surface and Coatings Technology. 2019. 364. P. 157 – 169. DOI: https://doi.org/10.1016/j.surfcoat.2019.02.078
[15] Harfouche M.M., Alidokht S.A., Islas Encalada A., Mungala V.N., Chromik R.R., Moreau C., Makowiec M.E. Scratch Adhesion Testing of Thick HVOF Thermal Sprayed Coatings. Journal of Thermal Spray Technology. 2024. 33 (4). P. 1158 – 1166. DOI: https://doi.org/10.1007/s11666-024-01741-3
[16] Vencl A., Arostegui S., Favaro G., Zivic F., Mrdak M., Mitrović S., Popovic V. Evaluation of adhesion/cohesion bond strength of the thick plasma spray coatings by scratch testing on coatings cross-sections. Tribology International. 2011. 44 (11). P. 1281 – 1288.
[17] Bayatlı A., Şahin E. F., Kocabaş M. Effect of boron carbide reinforcement on surface properties of electroless Ni–B and Ni–B–W coatings. Materials Chemistry and Physics. 2023. 305. P. 127899. DOI: https://doi.org/10.1016/j.matchemphys.2023.127899
[18] He D., Shang L., Lu Z., Zhang G., Wang L., Xue Q. Tailoring the mechanical and tribological properties of B4C/aC coatings by controlling the boron carbide content. Surface and Coatings Technology. 2017. 329. P. 11 – 18. DOI: https://doi.org/10.1016/j.surfcoat.2017.09.017
[19] Ramesh B., Elsheikh A.H., Satishkumar S., Shaik A.M., Djuansjah J., Ahmadein M., Alsaleh N.A. The Influence of boron carbide on the mechanical properties and bonding strength of B4C/Nickel 63 coatings of brake disc. Coatings. 2022. 12 (5). P. 663. DOI: https://doi.org/10.3390/coatings12050663
[20] Waichman S., Froim S., Zukerman I., Buzaglo M., Chachashvili M., Barzilai S. Magnetron sputtering of boron carbide coating on aluminum substrate – Experimental considerations for enhancing adhesion. Surfaces and Interfaces. 2023. 38. P. 102772. DOI: https://doi.org/10.1016/j.surfin.2023.102772
[21] Sirota V., Zaitsev S., Limarenko M., Prokhorenkov D., Lebedev M., Churikov A., Dan'shin A. Preparation of coatings with high infrared emissivity. Metal Working and Material Science. 2024. 26(2). P. 23 – 37. DOI: 10.17212/1994-6309-2024-26.2-23-37
Sirota V.V., Zaitsev S.V., Limarenko M.V., Churikov A.S., Podgornyi D.S. The effect of the introduction of B4C on the adhesive and cohesive properties of self-fluxing coatings. Construction Materials and Products. 2024. 7 (6). 5. https://doi.org/10.58224/2618-7183-2024-7-6-5