THE INFLUENCE OF SEVERAL TYPES OF RESINS ON THE DYNAMIC MECHANICAL PROPERTIES OF POLYMER MIXTURE BASED ON BUTYL RUBBER

https://doi.org/10.34031/2618-7183-2020-3-2-36-45
This work is devoted to the problem of developing vibration-damping polymer materials with high damping properties in a wide temperature range. The study of the effect of modifying additives on the strength, damping, adhesive and cohesive properties of a butyl rubber composite is the aim of this work. The task is to identify the actual temperature, frequency, dynamic and mechanical characteristics of a composite material based on butyl rubber depending on the type and concentration of resins. The key methods for studying this problem is the dynamic mechanical analysis method, aimed at obtaining information about changes in the dynamic properties of polymer materials (bond strength with metal when peeling samples of composites, determining the flow resistance of samples, determining the migration of plasticizer). Due to the established experimental dependences, it was found that the addition of resins (3% by weight) in the composition based on butyl rubber leads to an increase in the damping properties of composite materials, and an increase to (4.25% by weight) leads to their decrease. It was established that the obtained filled mixtures with a high damping peak and good adhesive and strength properties are mixtures with the addition of alkyl phenol-formaldehyde resins.
1. Cherkasov V.D., Tjurin M.V., Avdonin V.V. Issledovanie vlijanija napolnitelej i modifikatorov na dempfirujushhie svojstva materiala na osnove PVA. Inzhenernyj vestnik Dona. 2019. 9. URL: ivdon.ru/ru/magazine/archive/N8y2019/6138 (rus.)
2. Volockoj A.N., Jurkin Ju.V., Avdonin V.V. Issledovanie tangensa ugla mehanicheskih poter' i prochnosti vibropogloshhajushhih materialov na osnove jetilenvinilacetata, modificirovannyh kau-chukami. Inzhenernyj vestnik Dona. 2019. 8. URL: ivdon.ru/ru/magazine/archive/N8y2019/6136 (rus.)
3. Zhou S., Yang C., Hu J., He X., Zhang R. Damping Analysis of Some Inorganic Particles on Poly (bu-tyl-methacrylate). Materials. 2018. 11. P. 992.
4. Li Z., Lu X., Tao G., Guo J., Jiang H. Damping Elastomer with Broad Temperature Range Based on Ir-regular Networks Formed by End-Linking of Hydroxyl-Terminated Poly(dimethylsiloxane). Polymers ad-vanced technologies. 2015. 29. P. 2308 – 2316.
5. Study on the Damping of EVM based blends. Journal of. Applied Polymer Science. 2011. 120 (2). P. 1121 – 1125.
6. Kornev A.E., Bukanov A.M, Shevervjaev O.N. Jelastomernaja tehnologija. Moskva. 2009. 504 p. (rus.)
7. Zhang F., He G., Xu K., Wu H., Guo S., Zhang C. Damping Mechanism and Different Modes of Molecular Motion Through the Glass Transition of Chlorinated Butyl Rubber and Petroleum Resin Blends. Journal of Applied Polymer Science. 2014. 131 (40464).
8. Galimzjanova R.Ju., Makarov T.V., Vol'fson S.I. Vlijanie modifikatorov na svojstva neotver-zhdaemyh kompozicij na osnove butilkauchuka. Vestnik Kazanskogo tehnologicheskogo universiteta. 2009. 6. P. 168 – 172. (rus.)
9. Vibration damping sheet: pat. 5232785 SShA. N 927191; zajavl. 07.08.1992; opubl. 03.08.1993. 7 p.
10. Ohotina N.A., Vedjashkina D.A., Il'jazov M.F., Savel'ev A.P. Ocenka parametra rastvorimosti alkilformal'degidnyh smol. Vestnik Kazanskogo tehnologicheskogo universiteta 2011. 7. P. 110 – 114. (rus.)
11. Doncov A.A., Kanauzova A.A., Litvinova T.V. Kauchuk-oligomernye kompozicii v proizvodstve rezinovyh izdelij. M., 1986. 216 p. (rus.)
12. Nigmatullina A.I., Sharipov Je.N., Ohotina N.A. Opredelenie parametrov rastvorimosti i sovmestimosti s kauchukami smoly Pikar. Uspehi v himii i him. tehnologii. 2007. HHI. 6 (74). P. 37 – 39. (rus.)
13. Vibroshumopogloshhajushhij listovoj material: pat. 2368630 Ros. Federacija N2008112756/04; zajavl. 02.04.2008; opubl. 27.09.2009. Bjul. 27. 3 p. (rus.)
14. Light weight, high performance vibration-damping system: pat. 5840797 SShA N08/714657; zajavl. 16.09.1996; opubl. 24.11.1998. 10 p.
15. Murtazina L.I., Garifullin A.R., Nikul'cev I.A., Fathullin R.F. Vlijanie tehnologicheskih dobavok na svojstva neotverzhdaemyh germetikov na osnove jetilen-propilendienovogo kauchuka. Izvestija KGASU. 2015. 1. P. 134 – 142. (rus.)
16. Fengshun Zhang, Guansong He, Kangming Xu, Hong Wu, Shaoyun Guo, Chaoliang Zhang. Damping Mechanism and Different Modes of Molecular Motion Through the Glass Transition of Chlorinated Butyl Rubber and Petroleum Resin Blends. Journal of Applied Polymer Science. 2014. 10 (1002). 40464.
17. Wang Y., Zhou C., Yan H. Dynamic Mechanical Properties of Phenolic Resin. Chlorinated Butyl Rubber Composites. Journal of Macromolecular Science. 2014. R Part B. P. 813 – 819.
Tarasova O.I., Yurkin Yu.V., Toroshchin A.S. The influence of several types of resins on the dynamic mechanical properties of a polymer mixture based on butyl rubber. Construction Materials and Products. 2020. 3 (2). P. 36 – 45. https://doi.org/10.34031/2618-7183-2020-3-2-36-45