In accordance with the Sustainable Development Goals (SDGs) concept, there is a need to find technologies that would help make concrete production less energy intensive and more environmentally friendly. One technology involves substituting some mineral components in concrete with rapidly renewable plant-based alternatives. This study aims to establish the essential patterns among the concrete composition, micro-structure, and properties of cementitious composites modified with corn waste. Additionally, it seeks to explore the potential for producing high-quality composites using this waste material. To assess the effectiveness of this kind of waste, the strength of the cement-sand mortar, several characteristics like compressive strength, flexural durability and water absorption of hardened concrete were studied. It is established that introducing corn cob ash (CCA) to substitute a part of the cement up to 16% is justified and allows to obtain mortar and concrete with enhanced properties. CCA has a beneficial impact on the properties of Cement Sand Mortar (CSM) when replacing cement by no more than 15%. The maximum effect was achieved at 10% CCA, and the rise of compressive and flexural strength were 6.06% and 6.32%. In concrete with a CCA amount of 8%, the most impressive growth of compressive strength was 7.14%, and the lowest value of water absorption, which is 10.31% lower compared to the ordinary composition. Including CCA reduces the properties like workability, density of concrete mixtures, and the hardened composite density. The scientific results obtained prove the possibility of using CCA as an effective mineral pozzolanic additive that improves the properties of concrete.