The results of research on the development of technological solutions for the production of a new rubber-bitumen binder for asphalt concrete based on the use of industrial waste: used car tires, used car oil and microdispersed aluminosilicate spherical particles obtained from the processing of ash and slag waste (ASW) from thermal power plants are presented. The proposed technological solutions make it possible to obtain high-quality polymer additives for modifying the properties of road bitumen. The elements of novelty of the developed approach include the use, to obtain a granular modifier, of micro-sized hydrophobized aluminosilicate spheres, which are extracted as an additional product during the complex processing of ASW. The positive economic efficiency of technological solutions is ensured by the use of large rubber crumb (more than 8 mm) or rubber chips, their devulcanization together with hydrocarbon fractions of used engine oil and petroleum bitumen at a given temperature to form a gel-like mass, which is further subjected to mechanical grinding in a mill.
[1] Bakar S.K.A., Abdullah M.E., Kamal M.M., Abd Rahman R., Buhari R., Jaya R.P., Ahmad, K.A. The effect of crumb rubber on the physical and rheological properties of modified binder. Journal of Physics: Conference Series. IOP Publishing, 2018. 1049. 1. P. 012099.
[2] Belyaev P.S., Zabavnikov M.V., Malikov, O.G. To the question of obtaining the rubber-bitumen concentrate for asphalt-concrete road surfaces from the worn-out automobile tires (in Russian). Bulletin of Tambov State Technical University. 2008. 14. 2. P. 346 – 352.
[3] Makul N., Fediuk R., Amran H.M.M., Zeyad Abdullah M., Azevedo A., Klyuev S., Vatin N., Karelina M. Capacity to develop recycled aggregate concrete in south east asia. Buildings. 2021. 11 (6). 234.
[4] Fediuk R., Amran M., Klyuev S., Klyuev A. Increasing the performance of a fiber-reinforced concrete for protective facilities. Fibers. 2021. 9 (11). 64.
[5] Ferro G., Tulliani J.M., Lopez A., Jagdale P. New cementitious composite building material with enhanced toughness. Theoretical and applied fracture mechanics. 2015. 76. P. 67 – 74.
[6] Airey G.D. Fundamental binder and practical mixture evaluation of polymer modified bituminous materials. International Journal of Pavement Engineering. 2004. 5. 3. P. 137 – 151.
[7] Klyuev S., Fediuk R., Ageeva M., Fomina E., Klyuev A., Shorstova E., Sabitov L., Radaykin O., Anciferov S., Kikalishvili D., de Azevedo Afonso R.G., Vatin N. Technogenic fiber wastes for optimizing concrete. Materials. 2022. 15 (14). P. 5058.
[8] Yessenov M.K., Ramatullaeva L.I., Kolesnikov A.S., Ivakhniyuk G.K. Aspects of ecological modernization of technological equipment to reduce the level of dust from mining and processing production. MIAB. Mining informational and analytical bulletin. 2023. (10). P. 136 – 148.
[9] Kulikova E. Yu., Balovtsev S. V. Risk control system for the construction of urban underground structures. IOP Conference Series: Materials Science and Engineering. 2020. 962 (4). 042020.
[10] Meskhi B., Beskopylny A.N., Stel’makh S.A., Shcherban’ E.M., Mailyan L.R., Beskopylny N., Dotsenko N. Theoretical and Experimental Substantiation of the Efficiency of Combined-Reinforced Glass Fiber Polymer Composite Concrete Elements in Bending. Polymers. 2022. 14. 2324.
[11] Kolesnikova O., Vasilyeva N., Kolesnikov A., Zolkin A. Optimization of raw mix using technogenic waste to produce cement clinker. MIAB. Mining informational and analytical bulletin. 2022. (10-1). P. 103 – 115.
[12] Klyuev S., Fediuk R., Ageeva M., Fomina E., Klyuev A., Shorstova E., Zolotareva S., Shchekina N., Shapovalova A., Sabitov L. Phase formation of mortar using technogenic fibrous materials. Case Studies in Construction Materials. 2022. 16. P. e01099.
[13] Choquet F.S., Ista E.J. The determination of SBS, EVA and APP polymers in modified bitumens. Polymer modified asphalt binders. ASTM International, 1992. P. 35 – 49.
[14] Stel’makh S.A., Shcherban’ E.M., Beskopylny A.N., Mailyan L.R., Meskhi B., Razveeva I., Kozhakin A., Beskopylny N. Prediction of Mechanical Properties of Highly Functional Lightweight Fiber-Reinforced Concrete Based on Deep Neural Network and Ensemble Regression Trees Methods. Materials. 2022. 15. 6740.
[15] Belyaev V.P., Malikov O.G., Merkulov S.A., Belyaev P.S., Polushkin D.L., Frolov V.A. Improving energy efficiency of bitumen modification with reclaimed crumb rubber. Components of Scientific and Technological Progress. 2013. 1 (16). P. 75.
[16] Kotlyarevskiy A.A., Nezamaeva I.V. Asphalt concrete mixtures based on modified bituminous binder. Inzhenerny vestnik Dona. 2017. 45 (2(45). P. 144.
[17] Khristoforova A.A., Sokolova M.D. Mechanoactivation Treatment of Ground Vulcanizates. Chemistry for Sustainable Development. 2009. 17 (4). P. 429 – 432.
[18] Maryev V.A., Perlina J.V., Rudensky A.V., Blind B.M. Resource conservation in the construction and repair of road asphalt pavements due to the effective use of crumb rubber. Roads and bridges. 2015. 1 (33). P. 334 – 344.
[19] STO 61595504-002-2010. Composite material "UNIREM-001" on the basis of active rubber powder. Technical conditions
[20] STO 58528024.001-2013. Composite bituminous binders BITREK. Technical conditions.
[21] Rubber crumbs [Electronic resource]. Vostochno-Sibirskaya Pravda: network journal. 2011. URL https://www.vsp.ru/2011/07/08/rezinovye-kroshki/ (date of circulation: 01.10.2023)
[22] Ivanov S.A. Prospects of rubber-bitumen binders for improving the durability of highways. Young Scientist. 2013. 3. P. 60 – 62.
[23] Liu G., Liang Y., Chen H., Wang H., Komacka J., Gu X. Influence of the chemical composition and the morphology of crumb rubbers on the rheological and self-healing properties of bitumen. Construction and Building Materials. 2019. 210. P. 555 – 563.
[24] Modupe A.E., Atoyebi O.D., Basorun A.O., Gana A.J., Ramonu J.A., Raphael O.D. Development and performance evaluation of crumb rubber–Bio-oil modified hot mix asphalt for sustainable highway pavements. International Journal of Mechanical Engineering and Technology (IJMET). 2019. 10 (2). P. 273 – 287.
[25] Bilema M.A.M., Aman M.Y., Ahmad K.A. Investigating the rheological and physical properties for unaged of crumb rubber-modified binders containing warm mix asphalt additive. GCEC 2017: Proceedings of the 1st Global Civil Engineering Conference 1. Springer Singapore, 2019. P. 1389 – 1400.
[26] Loderer C., Partl M.N., Poulikakos L.D. Effect of crumb rubber production technology on performance of modified bitumen. Construction and Building Materials. 2018. 191. P. 1159 – 1171.
[27] Blażejowski K., Gawdzik B., Matynia T. Effect of recycled rubber on the properties of road bitumen. Journal of Chemistry. 2018. 2018. P. 1 – 6.
[28] Belyaev P.S., Malikov O.G., Zabavnikov M.V., Sokolov A.R. Improving the quality of petroleum bitumen by modification with products of processing of worn-out automobile tires. Vestnik of Tambov State Technical University. 2003. 9 (1). P. 63 – 69.
[2] Belyaev P.S., Zabavnikov M.V., Malikov, O.G. To the question of obtaining the rubber-bitumen concentrate for asphalt-concrete road surfaces from the worn-out automobile tires (in Russian). Bulletin of Tambov State Technical University. 2008. 14. 2. P. 346 – 352.
[3] Makul N., Fediuk R., Amran H.M.M., Zeyad Abdullah M., Azevedo A., Klyuev S., Vatin N., Karelina M. Capacity to develop recycled aggregate concrete in south east asia. Buildings. 2021. 11 (6). 234.
[4] Fediuk R., Amran M., Klyuev S., Klyuev A. Increasing the performance of a fiber-reinforced concrete for protective facilities. Fibers. 2021. 9 (11). 64.
[5] Ferro G., Tulliani J.M., Lopez A., Jagdale P. New cementitious composite building material with enhanced toughness. Theoretical and applied fracture mechanics. 2015. 76. P. 67 – 74.
[6] Airey G.D. Fundamental binder and practical mixture evaluation of polymer modified bituminous materials. International Journal of Pavement Engineering. 2004. 5. 3. P. 137 – 151.
[7] Klyuev S., Fediuk R., Ageeva M., Fomina E., Klyuev A., Shorstova E., Sabitov L., Radaykin O., Anciferov S., Kikalishvili D., de Azevedo Afonso R.G., Vatin N. Technogenic fiber wastes for optimizing concrete. Materials. 2022. 15 (14). P. 5058.
[8] Yessenov M.K., Ramatullaeva L.I., Kolesnikov A.S., Ivakhniyuk G.K. Aspects of ecological modernization of technological equipment to reduce the level of dust from mining and processing production. MIAB. Mining informational and analytical bulletin. 2023. (10). P. 136 – 148.
[9] Kulikova E. Yu., Balovtsev S. V. Risk control system for the construction of urban underground structures. IOP Conference Series: Materials Science and Engineering. 2020. 962 (4). 042020.
[10] Meskhi B., Beskopylny A.N., Stel’makh S.A., Shcherban’ E.M., Mailyan L.R., Beskopylny N., Dotsenko N. Theoretical and Experimental Substantiation of the Efficiency of Combined-Reinforced Glass Fiber Polymer Composite Concrete Elements in Bending. Polymers. 2022. 14. 2324.
[11] Kolesnikova O., Vasilyeva N., Kolesnikov A., Zolkin A. Optimization of raw mix using technogenic waste to produce cement clinker. MIAB. Mining informational and analytical bulletin. 2022. (10-1). P. 103 – 115.
[12] Klyuev S., Fediuk R., Ageeva M., Fomina E., Klyuev A., Shorstova E., Zolotareva S., Shchekina N., Shapovalova A., Sabitov L. Phase formation of mortar using technogenic fibrous materials. Case Studies in Construction Materials. 2022. 16. P. e01099.
[13] Choquet F.S., Ista E.J. The determination of SBS, EVA and APP polymers in modified bitumens. Polymer modified asphalt binders. ASTM International, 1992. P. 35 – 49.
[14] Stel’makh S.A., Shcherban’ E.M., Beskopylny A.N., Mailyan L.R., Meskhi B., Razveeva I., Kozhakin A., Beskopylny N. Prediction of Mechanical Properties of Highly Functional Lightweight Fiber-Reinforced Concrete Based on Deep Neural Network and Ensemble Regression Trees Methods. Materials. 2022. 15. 6740.
[15] Belyaev V.P., Malikov O.G., Merkulov S.A., Belyaev P.S., Polushkin D.L., Frolov V.A. Improving energy efficiency of bitumen modification with reclaimed crumb rubber. Components of Scientific and Technological Progress. 2013. 1 (16). P. 75.
[16] Kotlyarevskiy A.A., Nezamaeva I.V. Asphalt concrete mixtures based on modified bituminous binder. Inzhenerny vestnik Dona. 2017. 45 (2(45). P. 144.
[17] Khristoforova A.A., Sokolova M.D. Mechanoactivation Treatment of Ground Vulcanizates. Chemistry for Sustainable Development. 2009. 17 (4). P. 429 – 432.
[18] Maryev V.A., Perlina J.V., Rudensky A.V., Blind B.M. Resource conservation in the construction and repair of road asphalt pavements due to the effective use of crumb rubber. Roads and bridges. 2015. 1 (33). P. 334 – 344.
[19] STO 61595504-002-2010. Composite material "UNIREM-001" on the basis of active rubber powder. Technical conditions
[20] STO 58528024.001-2013. Composite bituminous binders BITREK. Technical conditions.
[21] Rubber crumbs [Electronic resource]. Vostochno-Sibirskaya Pravda: network journal. 2011. URL https://www.vsp.ru/2011/07/08/rezinovye-kroshki/ (date of circulation: 01.10.2023)
[22] Ivanov S.A. Prospects of rubber-bitumen binders for improving the durability of highways. Young Scientist. 2013. 3. P. 60 – 62.
[23] Liu G., Liang Y., Chen H., Wang H., Komacka J., Gu X. Influence of the chemical composition and the morphology of crumb rubbers on the rheological and self-healing properties of bitumen. Construction and Building Materials. 2019. 210. P. 555 – 563.
[24] Modupe A.E., Atoyebi O.D., Basorun A.O., Gana A.J., Ramonu J.A., Raphael O.D. Development and performance evaluation of crumb rubber–Bio-oil modified hot mix asphalt for sustainable highway pavements. International Journal of Mechanical Engineering and Technology (IJMET). 2019. 10 (2). P. 273 – 287.
[25] Bilema M.A.M., Aman M.Y., Ahmad K.A. Investigating the rheological and physical properties for unaged of crumb rubber-modified binders containing warm mix asphalt additive. GCEC 2017: Proceedings of the 1st Global Civil Engineering Conference 1. Springer Singapore, 2019. P. 1389 – 1400.
[26] Loderer C., Partl M.N., Poulikakos L.D. Effect of crumb rubber production technology on performance of modified bitumen. Construction and Building Materials. 2018. 191. P. 1159 – 1171.
[27] Blażejowski K., Gawdzik B., Matynia T. Effect of recycled rubber on the properties of road bitumen. Journal of Chemistry. 2018. 2018. P. 1 – 6.
[28] Belyaev P.S., Malikov O.G., Zabavnikov M.V., Sokolov A.R. Improving the quality of petroleum bitumen by modification with products of processing of worn-out automobile tires. Vestnik of Tambov State Technical University. 2003. 9 (1). P. 63 – 69.
Belyakov Y.S., Taskin А.V., Fedotov D.R., Makul N., Аlekseiko L.А., Zhdaneev О.V., Salanin D.А., Ivannikov S.I., Nagruzova L.P. Technology for the production of road bitumen modifier using aluminosilicate microspheres extracted from ash and slag energy waste. Construction Materials and Products. 2023. 6 (6). 3. https://doi.org/10.58224/2618-7183-2023-6-6-3