Русский
English
Use of clinker-free binders, such as geopolymers and various equivalents based on mineral additives, can significantly reduce the carbon footprint of the construction sector in the environment. The most promising and appropriate benchmark is the disposal of industrial waste of aluminosilicate oxide composition with subsequent mechanical and alkaline activation. For the first time, the microstructure of geopolymers based on aspiration cement dust and tuff has been comprehensively studied. The theoretical prerequisite for the creation of a binder system of such a concept is the synthesis of sufficiently strong and resistant to external manifestations of alkali metals, including the structures of frame aluminosilicates with a hidden crystalline structure. X-ray diffraction analysis of the obtained samples, as well as the results of scanning electron microscopy, electron dispersion spectrometry, differential-thermal analysis, ad infrared spectrometry confirm the presence in the geopolymer paste of products traditionally necessary for the hydration reaction: aqueous aluminosilicates, aluminates and silicates of sodium and calcium, quartz, calcite, feldspars similar to albite and orthoclase, micas, etc. The results obtained on the key results of the conducted studies confirm the high efficiency of the proposed technology and guarantee increased strength and durability of geopolymer concrete.
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19. Khater H.M., El Nagar A.M., Ezzat M. Optimization of Alkali Activated Grog. Ceramic Wastes Geopolymer Bricks // International Journal of Innovative Research in Science, Engineering and Technology. 2016. 5 (1). Р. 37 – 46. DOI: 10.15680/IJIRSET.2015.0501001.
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21. Amer I., Kohail M., El-Feky M.S., Rashad A. and Khalaf M.A. A Review on Alkali-Activated Slag Concrete. Ain Shams Engineering Journal. 2021. 12. P. 1475 – 1499.
22. Zemlyanskaya A.G., Lapunova К.А., Semenova M.Yu. Dry masonry mixtures based on siliceous opal-cristobalite rocks for clinker bricks. Construction Materials and Products. 2024. 7 (2). 5. https://doi.org/10.58224/2618-7183-2024-7-2-5
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24. Murtazaev S-A.Yu., Salamanova M.Sh., Saidumov M.S., Gatsaev Z.Sh., Alaskhanov A.Kh., Murtazaeva T.S-A. Development of geopolymer binders. Construction Materials and Products. 2024. 7 (6). 4. https://doi.org/10.58224/2618-7183-2024-7-6-4
25. Shcherban’ E.M., Beskopylny A.N., Stel’makh S.A., Mailyan L.R., Shilov A.A., Nguyen Quang Hiep, Yamin Song, Chernil’nik A.A., Elshaeva D.M. Study of thermophysical characteristics of variatropic concretes. Construction Materials and Products. 2024. 7 (4). 2. https://doi.org/10.58224/2618-7183-2024-7-4-2
26. Nesvetaev G.V., Koryanova Yu.I., Shut V.V. Specific heat dissipation of concrete and the risk of early cracking of massive reinforced concrete foundation slabs. Construction Materials and Products. 2024. 7 (4). 3. https://doi.org/10.58224/2618-7183-2024-7-4-3
27. Stel’makh S.A., Beskopylny A.N., Shcherban’ E.M., Mavzolevskii D.V., Drukarenko S.P., Chernil’nik A.A., Elshaeva D.M., Shilov A.A. Influence of Corn Cob Ash Additive on the Structure and Properties of Cement Concrete. Construction Materials and Products. 2024. 7 (3). P. 2. https://doi.org/10.58224/2618-7183-2024-7-3-2
28. Salamanova M.Sh., Gatsaev Z.Sh., Syzrantsev V.V. Investigation of the properties of alkaline binders with the addition of finely dispersed bentonite. Bulletin of the Moscow State University of Civil Engineering. 2022. Vol. 17. 8. Р. 1017 – 1026.
29. Salamanova M.Sh., Murtazaev S.-A.Yu. Cements of alkaline activation the possibility of reducing the energy intensity of building composites. Construction Materials] 2019. 7. P. 32 – 40. DOI: https://doi. org/10.31659/0585-430X-2019-772-7-32-40
2. Chen L., Wang Z., Wang Y. and Feng J. Preparation and Properties of Alkali Activated Metakaolin- Based Geopolymer. Materials. 2016. Vol. 9. Р. 767. doi: 10.3390/ma9090767.
3. Zhang Z., Provis J.L., Zou J., Reid A., Wang H. Toward an indexing approach to evaluate fly ashes for geopolymer manufacture. Cement and Concrete Research. 2016. Р. 163 – 173. DOI: 10.1016/j.cemconres.2016.04.007
4. Hardjito D., Wallah S., Sumajouw D., Rangan B. On the development of fly ash-based geopolymer concrete. ACJ Materials Journal. 2004. 101. Р. 467 – 472.
5. Davidovitz J. Geopolymer. Chemistry and applications. Saint-Quentin: Institute Geopolymer. 2008. 592 p.
6. Fadhil Nuruddin M., Demie S., Fareed Ahmed M., Nasir Shafiq Effect of Superplasticizer and NaOH molarity on workability, compressive strength and Microstructure Properties of Self- Compacting Geopolymer Concrete. World Academy of Science, Engineering and Technology. 2011. 75. Р. 908 – 914.
7. Ibragimov R.A., Shakirzyanov F.R., Kayumov R.A., Korolev E.V. Evaluation of the influence of an aggressive environment on the durability of the cement stone. Construction Materials and Products. 2024. 7 (2). 4. DOI: 10.58224/2618-7183-2024-7-2-4
8. Kotlyar V.D., Nebezhko Yu.I., Semenova M.Yu. Molding properties of clay mixtures in the soft mud brick manufacture. Construction Materials and Products. 2024. 7 (1). 5. DOI: 10.58224/2618-7183-2024-7-1-5
9. Muzalev S.V., Nikiforova E.V., Petrova O.A., Antonova O.V., Melnikova L.A. Recycling of municipal solid waste in construction. Construction Materials and Products. 2023. 6 (5). 7. DOI: 10.58224/2618-7183-2023-6-5-7
10. Vatin N.I., Petrosov D.V., Kalachev A.I., Lakhtinen P. The use of ash and ash and slag waste in construction. Civil Engineering magazine. 2011. 4. P. 16 – 21.
11. Hadbaatar A., Mashkin N.A., Stenina N.G. Study of Ash-Slag Wastes of Electric Power Plants of Mongolia Applied to their Utilization in Road Construction.. Procedia Engineering. 2016. P. 1558 – 1562. DOI: 10.1016/j.proeng.2016.07.111
12. Alex T.C., Nath S.K., Kumar S., Kalinkin A.M., Gurevich B.I., Kalinkina E.V., Tyukavkina V.V. Utilization of zinc slag through geopolymerization: influence of milling atmosphere. International Journal of Mineral Processing. 2013. 216. Р. 102 – 107. DOI: 10.1016/j.minpro.2013.06.001
13. Villa C., Pecina E.T., Torres R., Gomez L. Geopolymer synthesis using alkaline activation of natural zeolite. Construction and Building Materials. 2010. 24. Р. 2084 – 2090. DOI: 10.1016/j.conbuildmat.2010.04.052
14. Murtazayev S- A. Yu., Salamanova M.Sh., Mintsaev M.Sh., Bisultanov R.G. Fine-Grained Concretes with Clinker-Free Binders on an Alkali Gauging. Proceedings of the International Symposium "Engineering and Earth Sciences: Applied and Fundamental Research" dedicated to the 85th anniversary of H.I. Ibragimov (ISEES 2019). Atlantis Highlights in Material Sciences and Technology (AHMST). April 2019. 1. Р. 500 – 503. https://www.atlantis-press.com/proceedings/isees-19/125914231
15. Bataev D.K-S., Murtazayev S- A. Yu., Salamanova M.Sh., Viskhanov S.S. Utilization of Cement Kiln Dust in Production of Alkali-Activated Clinker-Free Binders. Proceedings of the International Symposium "Engineering and Earth Sciences: Applied and Fundamental Research" dedicated to the 85th anniversary of H.I. Ibragimov (ISEES 2019). Atlantis Highlights in Material Sciences and Technology (AHMST). April 2019. 1. Р. 457 – 460. https://www.atlantis-press.com/proceedings/isees-19/125914222
16. Dombrowski K. The Influence of Calcium Content on the Structure and Thermal Performance of Fly Ash Based Geopolymers. Journal of Materials Science. 2007. 42 (9). Р. 3033 – 3043. DOI: 10.1007/s10853-006-0532-7.
17. Pawlasova S., Skvara F. High-Temperature Properties of Geopolymer Materials. Аkali Activated Materials. 2008. Р. 523 – 525.
18. Khater H.M. Effect of firing temperatures on alkali activated Geopolymer mortar doped with MWCNT. Advances in Nano Research. 2015. 3 (4). Р. 225 – 242.
19. Khater H.M., El Nagar A.M., Ezzat M. Optimization of Alkali Activated Grog. Ceramic Wastes Geopolymer Bricks // International Journal of Innovative Research in Science, Engineering and Technology. 2016. 5 (1). Р. 37 – 46. DOI: 10.15680/IJIRSET.2015.0501001.
20. Nagajothi S., Elavenil S. Strength assessment of geopolymer concrete using M-sand. Int. J. Chem. Sci. 2016. 14 (1). Р. 115 – 126.
21. Amer I., Kohail M., El-Feky M.S., Rashad A. and Khalaf M.A. A Review on Alkali-Activated Slag Concrete. Ain Shams Engineering Journal. 2021. 12. P. 1475 – 1499.
22. Zemlyanskaya A.G., Lapunova К.А., Semenova M.Yu. Dry masonry mixtures based on siliceous opal-cristobalite rocks for clinker bricks. Construction Materials and Products. 2024. 7 (2). 5. https://doi.org/10.58224/2618-7183-2024-7-2-5
23. Klyuev S.V., Slobodchikova N.A., Saidumov M.S., Abumuslimov A.S., Mezhidov D.A., Khezhev T.A. Application of ash and slag waste from coal combustion in the construction of the earth bed of roads. Construction Materials and Products. 2024. 7 (6). 3. https://doi.org/10.58224/2618-7183-2024-7-6-3
24. Murtazaev S-A.Yu., Salamanova M.Sh., Saidumov M.S., Gatsaev Z.Sh., Alaskhanov A.Kh., Murtazaeva T.S-A. Development of geopolymer binders. Construction Materials and Products. 2024. 7 (6). 4. https://doi.org/10.58224/2618-7183-2024-7-6-4
25. Shcherban’ E.M., Beskopylny A.N., Stel’makh S.A., Mailyan L.R., Shilov A.A., Nguyen Quang Hiep, Yamin Song, Chernil’nik A.A., Elshaeva D.M. Study of thermophysical characteristics of variatropic concretes. Construction Materials and Products. 2024. 7 (4). 2. https://doi.org/10.58224/2618-7183-2024-7-4-2
26. Nesvetaev G.V., Koryanova Yu.I., Shut V.V. Specific heat dissipation of concrete and the risk of early cracking of massive reinforced concrete foundation slabs. Construction Materials and Products. 2024. 7 (4). 3. https://doi.org/10.58224/2618-7183-2024-7-4-3
27. Stel’makh S.A., Beskopylny A.N., Shcherban’ E.M., Mavzolevskii D.V., Drukarenko S.P., Chernil’nik A.A., Elshaeva D.M., Shilov A.A. Influence of Corn Cob Ash Additive on the Structure and Properties of Cement Concrete. Construction Materials and Products. 2024. 7 (3). P. 2. https://doi.org/10.58224/2618-7183-2024-7-3-2
28. Salamanova M.Sh., Gatsaev Z.Sh., Syzrantsev V.V. Investigation of the properties of alkaline binders with the addition of finely dispersed bentonite. Bulletin of the Moscow State University of Civil Engineering. 2022. Vol. 17. 8. Р. 1017 – 1026.
29. Salamanova M.Sh., Murtazaev S.-A.Yu. Cements of alkaline activation the possibility of reducing the energy intensity of building composites. Construction Materials] 2019. 7. P. 32 – 40. DOI: https://doi. org/10.31659/0585-430X-2019-772-7-32-40
Mintsaev M.Sh., Murtazaev S-A.Y., Salamanova M.Sh., Saidumov M.S., Murtazaev I.S-A. Features of the synthesis of construction geopolymer composites. Construction Materials and Products. 2025. 8 (2). 6. https://doi.org/10.58224/2618-7183-2025-8-2-6