At present, the primary objective of the road construction industry is to increase the service life of road pavements by implementing innovative technologies that meet modern standards of operational reliability. The key advantages of bitumen emulsions were analyzed, including improved adhesion and cohesion, environmental safety, resistance to water exposure, rapid curing and opening to traffic, applicability under cold conditions, as well as enhanced stability and durability. The research findings confirm the benefits of using bitumen emulsions in road construction, contributing to high-quality and long-lasting pavement performance. Studies were conducted on the modification of petroleum bitumen. The additional incorporation of Kulantau vermiculite into the composition enhances and stabilizes adhesion across a wide range of ambient humidity and temperature conditions. The adhesion process can be regarded as the adsorption of bitumen emulsion on the surface of mineral aggregates. Adsorption occurs through intermolecular interactions, and adhesion is improved by strengthening these interactions, which is achieved by increasing the activity of the bitumen emulsion through the introduction of additives with active functional groups. It was found that incorporating secondary polyethylene and Kulantau vermiculite into asphalt concrete leads to a noticeable decrease in the air void content. This reduction enhances the material’s resistance to moisture and freeze-thaw cycles.
1. Bhupendra S., Praveen K. Effect of polymer modification on the ageing properties of asphalt binders: chemical and morphological investigation. Constr. Build. Mater. 205. 2019. P. 633 – 641. DOI: 10.1016/j.conbuildmat.2019.02.050
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3. Cao G., Du T., Bai Y., Yang T., Zuo J. Effects of surfactant molecular structure on the stability of water in oil emulsion. Journal of Petroleum Science and Engineering. 196. 2021. DOI:10.1016/j.petrol.2020.107695
4. Sjadi S.El, Nederpel Q.A., Cotiuga I.M., Picken S.J., Besseling N.A.M., Mendes E., Lommerts B.J. BiopolymerScleroglucan as an Emulsion Stabilizer. Colloids and Surfaces A Physicochemical and Engineering Aspects. 2018. 546. Р. 326 – 333. DOI:10.1016/j.colsurfa.2018.02.035
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6. Yadykina V.V., Navolokina S.N., Gridchin A.M. The dependence of the modified bitumen properties on the amount of vinyl acetate in the sevilen composition. Mater. Sci. Forum. 2019. 974. P. 175 – 180. DOI: 10.4028/www.scientific.net/MSF.974.175
7. Bulanov P., Vdovin E., Stroganov V., Mavliev L., Juravlev I. Complex modification of bituminous binders by linear styrene-butadiene-styrene copolymer and sulfur. Proceedings of STCCE. International Scientific Conference on Socio-Technical Construction and Civil Engineering 2022: Lecture Notes in Civil Engineering. Switzerland. 2022. P. 405 – 413. DOI: 10.1007/978-3-031-14623-7_35
8. Qudaybergenov A. Improving the quality of bitumen emulsion in road construction. Modern Science and Researc. 2024. 3 (2). P. 416 – 418. DOI:10.5281/zenodo.10651808
9. Mazurek G., IwańskiM., BuczyńskP., HorodeckaR. Influence of innovative three-element binder on permanent deformations in recycled mixtures with emulsion and foamed bitumen Archives of Civil and Mechanical Engineering. 2021. 21. Р. 55. DOI:10.1007/s43452-021-00192-9.
10. Ming Liang, Shisong Ren, Weiyu Fan, Xue Xin, Jingtao Shi, Hui Luo. Rheological property and stability of polymer modified asphalt: effect of various vinyl acetate structures in EVA copolymers. Constr. Build. Mater. 2017. 137. P. 367 – 380. DOI: 10.1016/j.conbuildmat.2017.01.123
11. Galdina V.D. Modified Bitumens: Textbook, SibADI Publishing. Omsk. 2009. P. 230.
12. Yuliestyan A., García-Morales M., Moreno E., Carrera V., Partal P. Assessment of modified lignin cationic emulsifier for bitumen emulsions used in road paving. Materials and Design. 131. 2017. Р. 242-251. DOI: 10.1016/j.matdes.2017.06.024.
13. Onishchenko A., Stolyarova L., Bieliatynskyi A., Evaluation of the durability of asphalt concrete on polymer modified bitumen. E3S Web Conf. 2020. 157. 06005. DOI: 10.1051/e3sconf/202016403027.
14. Strokova V.V., Markova I.Y., Dmitrieva T.V., Shiman A.A. The influence of fly ashes from power plants on rheological properties of bitumen binder. Journal of Fundamental and Applied Sciences. 2016. 8 (2S). P. 1487 – 1498. DOI: 10.4314/jfas.v8i2s.293.2
15. Mignini C., Cardone F., Graziani A. Experimental study of bitumen emulsion-cement mortars: mechanical behavior and relation to mixtures. Materials and structures. 2018. 5 (6). 149. DOI: 10.1617 / s11527-018-127
16. Omar H.A., Yusoff N.I.M., Mubaraki M., Ceylan H., Effects of moisture damage on asphalt mixtures. J. Traffic Transp. Eng. (Engl. Ed.). 2020. 7 (5). P. 600 – 628. DOI: 10.1016/j.jtte.2020.07.001
17. e W., Jiang W., Li P., Yuan D., Shan J., Xiao J. Analysis of mechanism and time-temperature equivalent effects of asphalt binder in short-term aging, Constr. Build. Mater. 2019. DOI: 10.1016/j.conbuildmat.2019.04.197
18. Markov A.Yu., Strokova V.V., Bezrodnykh, A.A., Stepanenko М. Properties of fuel ashes of various types as components of bitumen emulsion. Building and reconstruction. 2020. 88. P. 67 – 76. DOI: 10.33979/2073-7416-2020-88-2-67-76
19. Rupal A., Sharma S.K., Tyagi G.D. Experimental investigation on mechanical properties of polyurethane modified bituminous waterproofing membrane. Materials Today: Proceedings. 27. 1. 2020. P. 467 – 474. DOI.org 10.1016/j.matpr.2019.11.278.
20. Bezrodnykh A.A., Strokova V.V., Markova I.Yu., Potapov D.Yu. Bitumen emulsions for road construction purposes, modified by fly ash. Stroitel’nye Materialy [Construction Materials]. 2021. 11. P. 59 – 66. DOI: https://doi.org/10.31659/0585-430X-2021-797-11-59-66
21. Kaldybekova Zh.B., Syrmanova K.K., Kovaleva A.Y., Polyfunctional Sorbents. Typography “Alem”. Shymkent. 2018. P. 174.
22. Syrmanova K., Kaldybekova Zh., Agabekova A., Baizhanova S. Influence of the chemical composition of Kulantau vermiculite on the structure of modified bitumen compositions. J. Compos. Sci. 2024. 8 (4). P. 118. DOI: 10.3390/jcs8040118
23. Methodological recommendations for the use of emulsifiers for bitumen emulsions “EMBIT”. Available at: https://propitki38.ru/wp-content/uploads/2023/02/2022-metodicheskie-rekomendaczii-emulgator-embit-bs.pdf
24. Garipov A.R., Makarov D.B., Khozin V.G., Stepanov S.V. Finely dispersed bitumen emulsion for the modification of cement concrete for road use. Construction and Geotechnics. 2022. 13 (3). P. 85 – 97. DOI: 10.15593/2224-9826/2022.3.08
25. Antonova I.I., Ayupov D.A., Khakimullin Y.N., Khozin V.G. Bitumen emulsions for waterproof and roof coverings. News KSUAE. 2023. 2. 1 (63). P. 6 – 14. DOI: 10.52409/20731523_2023_1_6
2. Yadykina V.V., Navolokina S.N., Gridchin A.M., The dependence of the modified bitumen properties on the amount of vinyl acetate in the sevilen composition. Mater. Sci. Forum. 974: 2019. P. 175 – 180. DOI: 10.4028/www.scientific.net/MSF.974.175
3. Cao G., Du T., Bai Y., Yang T., Zuo J. Effects of surfactant molecular structure on the stability of water in oil emulsion. Journal of Petroleum Science and Engineering. 196. 2021. DOI:10.1016/j.petrol.2020.107695
4. Sjadi S.El, Nederpel Q.A., Cotiuga I.M., Picken S.J., Besseling N.A.M., Mendes E., Lommerts B.J. BiopolymerScleroglucan as an Emulsion Stabilizer. Colloids and Surfaces A Physicochemical and Engineering Aspects. 2018. 546. Р. 326 – 333. DOI:10.1016/j.colsurfa.2018.02.035
5. Shakharbayev K.A., Izmailova G.G., Sivokhina E.S. Opyt primeneniya sherohovatoj poverhnostnoj obrabotki s bitumnoj emul'siej [Experience for the use of rough surface treatment with bitumen emulsion]. Vestnik Kazahskoj akademii transporta i kommunikacij im. M. Tynyshpaeva. 2018. 2 (105). P. 244 – 251. DOI: 10.52167/1609-1817
6. Yadykina V.V., Navolokina S.N., Gridchin A.M. The dependence of the modified bitumen properties on the amount of vinyl acetate in the sevilen composition. Mater. Sci. Forum. 2019. 974. P. 175 – 180. DOI: 10.4028/www.scientific.net/MSF.974.175
7. Bulanov P., Vdovin E., Stroganov V., Mavliev L., Juravlev I. Complex modification of bituminous binders by linear styrene-butadiene-styrene copolymer and sulfur. Proceedings of STCCE. International Scientific Conference on Socio-Technical Construction and Civil Engineering 2022: Lecture Notes in Civil Engineering. Switzerland. 2022. P. 405 – 413. DOI: 10.1007/978-3-031-14623-7_35
8. Qudaybergenov A. Improving the quality of bitumen emulsion in road construction. Modern Science and Researc. 2024. 3 (2). P. 416 – 418. DOI:10.5281/zenodo.10651808
9. Mazurek G., IwańskiM., BuczyńskP., HorodeckaR. Influence of innovative three-element binder on permanent deformations in recycled mixtures with emulsion and foamed bitumen Archives of Civil and Mechanical Engineering. 2021. 21. Р. 55. DOI:10.1007/s43452-021-00192-9.
10. Ming Liang, Shisong Ren, Weiyu Fan, Xue Xin, Jingtao Shi, Hui Luo. Rheological property and stability of polymer modified asphalt: effect of various vinyl acetate structures in EVA copolymers. Constr. Build. Mater. 2017. 137. P. 367 – 380. DOI: 10.1016/j.conbuildmat.2017.01.123
11. Galdina V.D. Modified Bitumens: Textbook, SibADI Publishing. Omsk. 2009. P. 230.
12. Yuliestyan A., García-Morales M., Moreno E., Carrera V., Partal P. Assessment of modified lignin cationic emulsifier for bitumen emulsions used in road paving. Materials and Design. 131. 2017. Р. 242-251. DOI: 10.1016/j.matdes.2017.06.024.
13. Onishchenko A., Stolyarova L., Bieliatynskyi A., Evaluation of the durability of asphalt concrete on polymer modified bitumen. E3S Web Conf. 2020. 157. 06005. DOI: 10.1051/e3sconf/202016403027.
14. Strokova V.V., Markova I.Y., Dmitrieva T.V., Shiman A.A. The influence of fly ashes from power plants on rheological properties of bitumen binder. Journal of Fundamental and Applied Sciences. 2016. 8 (2S). P. 1487 – 1498. DOI: 10.4314/jfas.v8i2s.293.2
15. Mignini C., Cardone F., Graziani A. Experimental study of bitumen emulsion-cement mortars: mechanical behavior and relation to mixtures. Materials and structures. 2018. 5 (6). 149. DOI: 10.1617 / s11527-018-127
16. Omar H.A., Yusoff N.I.M., Mubaraki M., Ceylan H., Effects of moisture damage on asphalt mixtures. J. Traffic Transp. Eng. (Engl. Ed.). 2020. 7 (5). P. 600 – 628. DOI: 10.1016/j.jtte.2020.07.001
17. e W., Jiang W., Li P., Yuan D., Shan J., Xiao J. Analysis of mechanism and time-temperature equivalent effects of asphalt binder in short-term aging, Constr. Build. Mater. 2019. DOI: 10.1016/j.conbuildmat.2019.04.197
18. Markov A.Yu., Strokova V.V., Bezrodnykh, A.A., Stepanenko М. Properties of fuel ashes of various types as components of bitumen emulsion. Building and reconstruction. 2020. 88. P. 67 – 76. DOI: 10.33979/2073-7416-2020-88-2-67-76
19. Rupal A., Sharma S.K., Tyagi G.D. Experimental investigation on mechanical properties of polyurethane modified bituminous waterproofing membrane. Materials Today: Proceedings. 27. 1. 2020. P. 467 – 474. DOI.org 10.1016/j.matpr.2019.11.278.
20. Bezrodnykh A.A., Strokova V.V., Markova I.Yu., Potapov D.Yu. Bitumen emulsions for road construction purposes, modified by fly ash. Stroitel’nye Materialy [Construction Materials]. 2021. 11. P. 59 – 66. DOI: https://doi.org/10.31659/0585-430X-2021-797-11-59-66
21. Kaldybekova Zh.B., Syrmanova K.K., Kovaleva A.Y., Polyfunctional Sorbents. Typography “Alem”. Shymkent. 2018. P. 174.
22. Syrmanova K., Kaldybekova Zh., Agabekova A., Baizhanova S. Influence of the chemical composition of Kulantau vermiculite on the structure of modified bitumen compositions. J. Compos. Sci. 2024. 8 (4). P. 118. DOI: 10.3390/jcs8040118
23. Methodological recommendations for the use of emulsifiers for bitumen emulsions “EMBIT”. Available at: https://propitki38.ru/wp-content/uploads/2023/02/2022-metodicheskie-rekomendaczii-emulgator-embit-bs.pdf
24. Garipov A.R., Makarov D.B., Khozin V.G., Stepanov S.V. Finely dispersed bitumen emulsion for the modification of cement concrete for road use. Construction and Geotechnics. 2022. 13 (3). P. 85 – 97. DOI: 10.15593/2224-9826/2022.3.08
25. Antonova I.I., Ayupov D.A., Khakimullin Y.N., Khozin V.G. Bitumen emulsions for waterproof and roof coverings. News KSUAE. 2023. 2. 1 (63). P. 6 – 14. DOI: 10.52409/20731523_2023_1_6
Syrmanova K.K., Tuleuov R.M., Kaldybekova Zh.B., Baizhanova Sh.B., Kolesnikova O.G., Zhumayev Zh.Zh., Nigmetov M.Zh., Yesbolay G.I. Development of a modified bitumen emulsion to enhance
the operational properties of asphalt concrete. Construction Materials and Products. 2025. 8 (3). 1. https://doi.org/10.58224/2618-7183-2025-8-3-1
the operational properties of asphalt concrete. Construction Materials and Products. 2025. 8 (3). 1. https://doi.org/10.58224/2618-7183-2025-8-3-1

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