Русский
English
This paper presents data on the synthesis of cement grinding intensifiers produced from oil and gas processing wastes, namely secondary alkanolamines. The results of physicochemical characterization of the raw materials are reported, including the optimal purification conditions for the wastes and the synthesis parameters of the grinding intensifiers, as well as the physicochemical properties of the obtained products. It was found that the optimal conditions for producing the grinding intensifier involve conducting the reaction at 45°C for 6 hours with a 1:9 component ratio. The effects of the synthesized intensifiers on the cement clinker grinding process were investigated, including their influence on particle size distribution and the mineralogical composition of modified cements. The particles of the modified cement were shown to exhibit a predominantly spherical morphology; the maximum laser diffraction value reached 13.5%, the intensity was 88%, and the particle size was mainly around 2 μm (more than 53.5%), while the fraction of particles within the 100-200 μm range was 4.87%. X-ray diffraction and differential thermal analysis revealed that hydration of the modified cement is accompanied by a slight decrease in the diffraction intensity of calcium silicate phases (C2S and C3S), whereas an increase in the diffraction intensity of calcium hydroxide (Ca(OH)2) was observed. This indicates the formation of calcium hydroxide and calcium silicate hydrate (C-S-H) during cement hydration. The diffraction peaks of these phases were detected within the ranges of 30-33° 2θ and 40-45° 2θ. In addition, the presence of aluminate (C3A) and ferrite (C4AF) phases within 40-45° 2θ corresponds to calcium carbonate (CaCO3) observed in low-intensity regions between 29.4° 2θ and 48.5° 2θ, which is associated with CO2 absorption from the atmosphere. These changes reflect phase transformations during hydration and the formation of phases that are critical for strength development. The optimal dosage of the grinding intensifier in the cement composition was determined to be 0.02 wt.% (based on dry residue).
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15. Auyesbek S.T., Sarsenbayev N.B., Sarsenbayev B.K., Khudyakova T.M., Aimenov Zh.T., Abdiramanova K.S., Aubakirova T.S., Sauganova G.R., Karshyga G.O., Nurbaeva F.K. Thermal insulating materials based on Magnesium-containing technogenic raw Materials. Rasayan Journal of Chemistry. 2023. 16 (1). P. 413 – 421. https://doi.org/10.31788/RJC.2023.1618327
16. Muratov B., Shapalov S., Syrlybekkyzy S., Volokitina I., Zhunisbekova D., Takibayeva G., Nurbaeva F., Aubakirova T., Nurshakhanova L., et al. Physico-Chemical Study of the Possibility of Utilization of Coal Ash by Processing as Secondary Raw Materials to Obtain a Composite Cement Clinker. Journal of Composites Science. 2023. 7 (6). P. 234. https://doi.org/10.3390/jcs7060234
17. Mishra R.K., Weibel M., Müller T., Heinz H., Flatt R.J. Energy-effective grinding of inorganic solids using organic additives. Chimia. 2017. 71 (7-8). P. 451 – 460. https://doi.org/10.2533/chimia.2017.451
18. Kuldeyev E., Begentayev M., Sarsenbayev B., Syrlybekkyzy S., Agabekova A., Bayamirova R., Togasheva A., Zholbassarova A., Koishina A., et al. Investigation of the Possibility of Utilizing Man-Made Waste to Produce Composite Binders. Journal of Composites Science. 2025. 9 (10). P. 531. https://doi.org/10.3390/jcs9100531
19. Marazzani B., Bürge C., Kurz C., Müller T. Dialkanolamines as additives for grinding of solids. 2015.
20. Zhanikulov N., Khudyakova T., Taimassov B., Sarsenbayev B., Dauletiarov M., Karshygayev R. Receiving Portland Cement from Technogenic Raw Materials of South Kazakhstan. Eurasian Chemico-Technological Journal. 2019. 21 (4). P. 333 – 340. https://doi.org/10.18321/ectj890
21. Sapargaliyeva B.O., Bychkov A.Yu., Alferyeva Ya.O., Syrlybekkyzy S., Altybaeva Zh.K., Nurshakhanova L.K., Seidaliyeva L.K., Suleimenova B.S., Zhidebayeva A.E., Zhanikulov N.N., Suleimenova T.N., Koshkarbayeva Sh.K., Suigenbayeva A.Zh. Thermodynamic modeling of the formation of the main minerals of cement clinker and zinc fumes in the processing of toxic technogenic waste of the metallurgical industry. Rasayan Journal of Chemistry. 2022. 15 (3). P. 2181 – 2187. https://doi.org/10.31788/RJC.2022.1536230
22. Amiraliyev B., Taimasov B., Potapova E., Sarsenbaev B., Begentayev M., Dauletiyarov M., Kuandykova A., Abdullin A., Ainabekov N., Auyesbek S. Heat Treatment of Clay Shales and Their Utilization as Active Mineral Additives for the Production of Composite Cements. Journal of Composites Science. 2025. 9 (6). P. 269. https://doi.org/10.3390/jcs9060269
23. Auyesbek S., Sarsenbayev N., Abduova A., Sarsenbayev B., Uderbayev S., Aimenov Z., Kenzhaliyeva G., Akishev U., Aubakirova T., Sauganova G., et al. Man-Made Raw Materials for the Production of Composite Silicate Materials Using Energy-Saving Technology. Journal of Composites Science. 2023. 7 (3). P. 124. https://doi.org/10.3390/jcs7030124
24. Kuandykova A., Taimasov B., Potapova E., Sarsenbaev B., Begentayev M., Kuldeyev E., Dauletiyarov M., Zhanikulov N., Amiraliyev B., et al. Production of Composite Cement Clinker Based on Industrial Waste. Journal of Composites Science. 2024. 8 (7). P. 257. https://doi.org/10.3390/jcs8070257
25. Ismailov A.A., Baybolov K.S., Ristavletov R.A., Kopzhasarov B.T., Kambarov M.A., Ussipbaev U.A., Kudabayev R.B., Mominova S.M. Effect of Cost-Effective Alkaline Additives on the Hydration of Slag-Cement Mixtures. Journal of Advanced Concrete Technology. 2018. 16 (9). P. 429 – 440. https://doi.org/10.3151/jact.16.429
26. Ma S., Li W., Zhang S., Hu Y., Shen X. Study on the hydration and microstructure of Portland cement containing diethanol-isopropanolamine. Cement and Concrete Research. 2015. 67. P. 122 – 130. https://doi.org/10.1016/j.cemconres.2014.09.002
27. Xu Z., Li W., Sun J., Hu Y., Xu K., Ma S., Shen X. Research on cement hydration and hardening with different alkanolamines. Construction and Building Materials. 2017. 141. P. 296 – 306. https://doi.org/10.1016/j.conbuildmat.2017.03.010
28. Khudyakova T.M., Kenzhibaeva G.S., Kutzhanova A.N., Iztleuov G.M., Zhanikulov N.N., Kolesnikova O.G., Mynbaeva E. Optimization of Raw Material Mixes in Studying Mixed Cements and Their Physicomechnical Properties. Refractories and Industrial Ceramics. 2019. 60 (1). P. 76 – 81. https://doi.org/10.1007/s11148-019-00312-2
29. Huang H., Li X., Avet F., Hanpongpun W., Scrivener K. Strength-promoting mechanism of alkanolamines on limestone-calcined clay cement and the role of sulfate. Cement and Concrete Research. 2021. 147. P. 106527. https://doi.org/10.1016/j.cemconres.2021.106527
30. Khudyakova T.M., Kolesnikova O.G., Zhanikulov N.N., Botabaev N.E., Kenzhibaeva G.S., Iztleuov G.M., Suigenbaeva A.Z., Kutzhanova A.N., Ashirbaev H.A., Kolesnikova V.A. Low-base cement, problems and advantages of its use. Refractories and Industrial Ceramics. 2021. 62 (1). P. 3 – 9. https://doi.org/10.17073/1683-4518-2021-7-3-9
31. Zou F., Tan H., He X., Ma B., Deng X., Zhang T., Mei J., Liu X., Qi H. Effect of triisopropanolamine on compressive strength and hydration of steaming-cured cement-fly ash paste. Construction and Building Materials. 2018. 192. P. 836 – 845. https://doi.org/10.1016/j.conbuildmat.2018.10.142
2. Juenger M.C.G., Snellings R., Bernal S.A. Supplementary cementitious materials: new sources, characterization, and performance insights. Cement and Concrete Research. 2019. 122. P. 257 – 273. https://doi.org/10.1016/j.cemconres.2019.05.008
3. Snellings R. Assessing, understanding and unlocking supplementary cementitious materials. RILEM Technical Letters. 2016. 1. P. 50 – 55.
4. https://doi.org/10.21809/rilemtechlett.2016.12
5. Pan D., Li L., Tian X., Wu Y., Cheng N., Yu H. A review on lead slag generation, characteristics, and utilization. Resources, Conservation and Recycling. 2019. 146. P. 140 – 155. https://doi.org/10.1016/j.resconrec.2019.03.036
6. Gholizadeh A., Horckmans L., Snellings R., Peys A., Teck P., Maier J., Friedrich B., Klejnowska K. Use of Treated Non-Ferrous Metallurgical Slags as Supplementary Cementitious Materials in Cementitious Mixtures. Applied Sciences. 2021. 11 (9). P. 4028. https://doi.org/10.3390/app11094028
7. Sivakumar P.P., Matthys S., De Belie N., Gruyaert E. Reactivity Assessment of Modified Ferro Silicate Slag by R3 Method. Applied Sciences. 2021. 11 (1). P. 366. https://doi.org/10.3390/app11010366
8. Hallet V., Pedersen M.T., Lothenbach B., Winnefeld F., De Belie N., Pontikes Y. Hydration of blended cement with high volume iron-rich slag from non-ferrous metallurgy. Cement and Concrete Research. 2022. 151. P. 106624. https://doi.org/10.1016/j.cemconres.2021.106624
9. Sergeeva I.V., Botabaev N.E., Al’zhanova A.Zh., Ashirbaev Kh.A. Chemical and phase transitions in oxidized manganese ore in the presence of carbon. Steel in Translation. 2017. 47 (9). P. 605 – 609. https://doi.org/10.3103/S0967091217090078
10. Sarsenbayev B., Murtazaev S.-A., Salamanova M., Kuldeyev E., Saidumov M., Sarsenbayev N., Auyesbek S., Sauganova G., Abduova A. Utilization of Anthropogenic and Natural Waste to Produce Construction Raw Materials. Sustainability. 2025. 17 (7). P. 2791. https://doi.org/10.3390/su17072791
11. Auyesbek S., Sarsenbayev B., Lesovik V., Kolesnikova O., Begentayev M., Kuldeyev E., Tulaganov B., Sauganova G., Zhumayev Z. Studies on the Production of a Ground Silicate Composite Based on a Mineral Slag Binder with the Disposal of Industrial Waste. Journal of Composites Science. 2025. 9 (5). P. 225. https://doi.org/10.3390/jcs9050225
12. Zhanikulov N., Taimasov B., Shal A. Influence of industrial waste on the structure of environmentally friendly cement clinker. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2022. 323 (4). P. 84 – 91. https://doi.org/10.31643/2022/6445.44
13. Ristavletov R.A., Baybolov K.S., Kopzhasarov B.T., Kambarov M.A., Imanaliev K.E., Ibraimbayeva G.B., Abshenov Kh.A., Kudabayev R.B. Effective multifunctional additives for concrete based on the wastes of the oil industry. Structural Concrete. 2019. 20 (6). P. 1–10. https://doi.org/10.1002/suco.201700284
14. Kolesnikov A.S., Zhanikulov N.N., Kuraev R.M. Thermodynamic modeling of the synthesis of the main minerals of cement clinker from technogenic raw materials. Kompleksnoe Ispolzovanie Mineralnogo Syra = Complex Use of Mineral Resources. 2021. 318 (3). P. 24 – 34. https://doi.org/10.31643/2021/6445.25
15. Auyesbek S.T., Sarsenbayev N.B., Sarsenbayev B.K., Khudyakova T.M., Aimenov Zh.T., Abdiramanova K.S., Aubakirova T.S., Sauganova G.R., Karshyga G.O., Nurbaeva F.K. Thermal insulating materials based on Magnesium-containing technogenic raw Materials. Rasayan Journal of Chemistry. 2023. 16 (1). P. 413 – 421. https://doi.org/10.31788/RJC.2023.1618327
16. Muratov B., Shapalov S., Syrlybekkyzy S., Volokitina I., Zhunisbekova D., Takibayeva G., Nurbaeva F., Aubakirova T., Nurshakhanova L., et al. Physico-Chemical Study of the Possibility of Utilization of Coal Ash by Processing as Secondary Raw Materials to Obtain a Composite Cement Clinker. Journal of Composites Science. 2023. 7 (6). P. 234. https://doi.org/10.3390/jcs7060234
17. Mishra R.K., Weibel M., Müller T., Heinz H., Flatt R.J. Energy-effective grinding of inorganic solids using organic additives. Chimia. 2017. 71 (7-8). P. 451 – 460. https://doi.org/10.2533/chimia.2017.451
18. Kuldeyev E., Begentayev M., Sarsenbayev B., Syrlybekkyzy S., Agabekova A., Bayamirova R., Togasheva A., Zholbassarova A., Koishina A., et al. Investigation of the Possibility of Utilizing Man-Made Waste to Produce Composite Binders. Journal of Composites Science. 2025. 9 (10). P. 531. https://doi.org/10.3390/jcs9100531
19. Marazzani B., Bürge C., Kurz C., Müller T. Dialkanolamines as additives for grinding of solids. 2015.
20. Zhanikulov N., Khudyakova T., Taimassov B., Sarsenbayev B., Dauletiarov M., Karshygayev R. Receiving Portland Cement from Technogenic Raw Materials of South Kazakhstan. Eurasian Chemico-Technological Journal. 2019. 21 (4). P. 333 – 340. https://doi.org/10.18321/ectj890
21. Sapargaliyeva B.O., Bychkov A.Yu., Alferyeva Ya.O., Syrlybekkyzy S., Altybaeva Zh.K., Nurshakhanova L.K., Seidaliyeva L.K., Suleimenova B.S., Zhidebayeva A.E., Zhanikulov N.N., Suleimenova T.N., Koshkarbayeva Sh.K., Suigenbayeva A.Zh. Thermodynamic modeling of the formation of the main minerals of cement clinker and zinc fumes in the processing of toxic technogenic waste of the metallurgical industry. Rasayan Journal of Chemistry. 2022. 15 (3). P. 2181 – 2187. https://doi.org/10.31788/RJC.2022.1536230
22. Amiraliyev B., Taimasov B., Potapova E., Sarsenbaev B., Begentayev M., Dauletiyarov M., Kuandykova A., Abdullin A., Ainabekov N., Auyesbek S. Heat Treatment of Clay Shales and Their Utilization as Active Mineral Additives for the Production of Composite Cements. Journal of Composites Science. 2025. 9 (6). P. 269. https://doi.org/10.3390/jcs9060269
23. Auyesbek S., Sarsenbayev N., Abduova A., Sarsenbayev B., Uderbayev S., Aimenov Z., Kenzhaliyeva G., Akishev U., Aubakirova T., Sauganova G., et al. Man-Made Raw Materials for the Production of Composite Silicate Materials Using Energy-Saving Technology. Journal of Composites Science. 2023. 7 (3). P. 124. https://doi.org/10.3390/jcs7030124
24. Kuandykova A., Taimasov B., Potapova E., Sarsenbaev B., Begentayev M., Kuldeyev E., Dauletiyarov M., Zhanikulov N., Amiraliyev B., et al. Production of Composite Cement Clinker Based on Industrial Waste. Journal of Composites Science. 2024. 8 (7). P. 257. https://doi.org/10.3390/jcs8070257
25. Ismailov A.A., Baybolov K.S., Ristavletov R.A., Kopzhasarov B.T., Kambarov M.A., Ussipbaev U.A., Kudabayev R.B., Mominova S.M. Effect of Cost-Effective Alkaline Additives on the Hydration of Slag-Cement Mixtures. Journal of Advanced Concrete Technology. 2018. 16 (9). P. 429 – 440. https://doi.org/10.3151/jact.16.429
26. Ma S., Li W., Zhang S., Hu Y., Shen X. Study on the hydration and microstructure of Portland cement containing diethanol-isopropanolamine. Cement and Concrete Research. 2015. 67. P. 122 – 130. https://doi.org/10.1016/j.cemconres.2014.09.002
27. Xu Z., Li W., Sun J., Hu Y., Xu K., Ma S., Shen X. Research on cement hydration and hardening with different alkanolamines. Construction and Building Materials. 2017. 141. P. 296 – 306. https://doi.org/10.1016/j.conbuildmat.2017.03.010
28. Khudyakova T.M., Kenzhibaeva G.S., Kutzhanova A.N., Iztleuov G.M., Zhanikulov N.N., Kolesnikova O.G., Mynbaeva E. Optimization of Raw Material Mixes in Studying Mixed Cements and Their Physicomechnical Properties. Refractories and Industrial Ceramics. 2019. 60 (1). P. 76 – 81. https://doi.org/10.1007/s11148-019-00312-2
29. Huang H., Li X., Avet F., Hanpongpun W., Scrivener K. Strength-promoting mechanism of alkanolamines on limestone-calcined clay cement and the role of sulfate. Cement and Concrete Research. 2021. 147. P. 106527. https://doi.org/10.1016/j.cemconres.2021.106527
30. Khudyakova T.M., Kolesnikova O.G., Zhanikulov N.N., Botabaev N.E., Kenzhibaeva G.S., Iztleuov G.M., Suigenbaeva A.Z., Kutzhanova A.N., Ashirbaev H.A., Kolesnikova V.A. Low-base cement, problems and advantages of its use. Refractories and Industrial Ceramics. 2021. 62 (1). P. 3 – 9. https://doi.org/10.17073/1683-4518-2021-7-3-9
31. Zou F., Tan H., He X., Ma B., Deng X., Zhang T., Mei J., Liu X., Qi H. Effect of triisopropanolamine on compressive strength and hydration of steaming-cured cement-fly ash paste. Construction and Building Materials. 2018. 192. P. 836 – 845. https://doi.org/10.1016/j.conbuildmat.2018.10.142
Ristavletov R.A., Auyesbekova M.A., Karimov M.U., Kambarov M.A., Kasimova G.A., Kudabayev R.B., Bektursunova A.K., Artykova Zh.K. Investigation of the synthesis of a grinding intensifier from secondary raw materials and its influence on the microstructural development of cement stone. Construction Materials and Products. 2026. 9 (1). 9. https://doi.org/10.58224/2618-7183-2026-9-1-9