Keywords: adsorption

ADSORPTION OF SPINDLE OIL BY NATIVE AND THERMAL MODIFIED CHESTNUT TREE WASTE

https://doi.org/10.34031/2618-7183-2018-1-1-4-11
Abstract
Adsorption is a widespread and effective way of treating sewage containing petroleum products. To implement this method, one of the best sorbents is activated carbon. However, sorbents based on activated coals are of high cost and require further regeneration, which significantly increases the cost of water treatment. In addition, during the regeneration of such sorption materials secondary toxic waste is formed, which also create environmental problems. Therefore, the development of new efficient and inexpensive sorption materials, especially on the base of a variety of wastes, is an urgent task.
For research, we used tree waste of the genus of horse chestnut (Latin Aésculus hippocastanum L.). Horse chestnut is widespread in the midland of the Russian Federation, CIS countries, Southern Europe. According to municipal services about 5.000 chestnut trees grow on the territory of a city with a population of about 400.000 people and tree waste of the trees covering streets and square every year. Tree waste is nowhere used and removed to landfills.
Extraction of I-20A spindle oil from model emulsions by native and thermal modified chestnut tree waste as a sorption material in industry was carried out because this oil is a widely used petroleum product. The physicochemical properties of tree waste, such as bulk density, humidity, ash content, pH of aqueous extract, specific surface area are studied.
Before extraction, the chestnut tree waste was ground to a size of 3-5 mm. Thermal treatment was carried out in a drying cabinet of the type SNOL and muffle furnace in the temperature range 100-500 C. It is established that during the thermal treatment the specific surface area of the sorption material increases from 2.6 to 27.9 m2/ g. The surface of micro relief structure changes in the direction of increasing roughness and defectiveness; sorption material acquires hydrophobic properties. The recommended thermal treatment temperature is 200 C. The efficiency of cleaning model emulsions is 91%.
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STUDY OF SORPTION OF NICKEL ION WITH FIBROUS ADSORBENTS

https://doi.org/10.34031/2618-7183-2018-1-1-12-20
Abstract
Technological processes of processing of metal products and galvanic production are characterized by large volumes of wastewater containing ions of heavy metals, in particular as a result of Nickel plating products in wastewater in the predominant amount fall ions Ni2+. To assess the possibility of removing pollution from this type of wastewater, the process of adsorption purification of model Nickel-containing wastewater was investigated. As adsorbents modified nitrogen-containing polyvinyl alcohol, polycaproamide, hydrocellulose fiber were used. Modification of this type of fibers allows fixing functionally active groups on the surface of adsorbent. It is established that the fibrous adsorbents have a high adsorption capacity towards Nickel ion(II), the magnitude of adsorption is in the range of 80-100 mg/g. The predominant mechanism is monomolecular chemisorption. Adsorption proceeds at high speeds, the balance is achieved in the first 20 minutes of the process. The effect of pH on complex formation in the phase of adsorbents is revealed. It is shown that in a strongly acidic medium the purification efficiency is small, the increase in pH leads to increased adsorption properties of fibers. The optimal value of the acidity of the solution are pH values above 5. A decrease in the amount of coordinated nitrogen with an increase in pH was determined. In assessing the selectivity of fibers with respect to Ni2+ in the presence of Zn2+ and Cu2+, the influence of matrix polymer effect was revealed. Adsorption on polyvinyl alcohol and polycaproamide fibers showed that the influence of zinc ions(II) on the adsorption of Nickel (II) increases with its concentration in the solution, and hydrate cellulose fiber has a higher selectivity with respect to Zn2+ion. The presence of Cu2+ leads to a significant decrease in the efficiency of model wastewater treatment from Nickel ions (II) on all types of adsorbents studied.
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