2026

Archives Journal Construction Materials and Products Vol. 9

Organomineral thermal insulation composite with reduced flammability based on sodium silicate and a polyurethane foam matrix

https://doi.org/10.58224/2618-7183-2026-9-4-7
Abstract
This article is devoted to the study of an organomineral thermal insulation composite based on a rigid polyurethane foam (PUF) matrix and a flammability-reducing silicate component-sodium metasilicate pentahydrate (Na2SiO3•5H2O, 0.9-1.25 mm fraction). The physicochemical regularities of the interaction between the silicate component and isocyanate, the fire-retardant mechanism of the silicate component, and its effect on the thermal properties and flammability of the composite have been investigated.
A chemical interaction between the isocyanate functional groups of the reactive mixture and the water contained in the silicate component was established to occur at the phase boundary.
The fire-retardant mechanism of the silicate component consists in the endothermic release of crystallization water (70-170 ℃), which induces intumescence of the metasilicate, resulting in the formation of a porous heat-insulating barrier.
The silicate component does not alter the fundamental decomposition mechanism of the polyurethane, yet it shifts the stages of thermo-oxidative degradation to lower temperatures (by 15-85 ℃). The final residue increases up to 8.1 times (from 3.6 to 29.1 wt%), which directly corresponds to the contribution of the dehydrated silicate.
Flammability tests demonstrated that when the silicate component content exceeds 45%, the material achieves a UL 94 V 0 rating, and the limiting oxygen index (LOI) increases from 17.8 to 26.6 at a 90% silicate component loading.
The obtained results substantiate the effectiveness of using sodium silicate crystalline hydrate as a fire-retardant additive, and it can be recommended for the development of composites based on other polymer matrices.
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Compressive strength and durability check of pre-soaked basalt fiber reinforced concrete under dynamic loading

https://doi.org/10.58224/2618-7183-2026-9-4-8
Abstract
This study examined the impact of dry and pre-soaked basalt fibers on the durability, mechanical, and dynamic properties of concrete. Macro (UMA, PMA) and micro (UMI, PMI) fibers were used at a set dosage of 2%, where water-conditioned pre-soaked fibers were soaked for 24 hours before use. Experimental tests were slump, density, compressive strength, split tensile strength, modulus of elasticity, flexural strength, chloride ion diffusion, and dynamic modulus of elasticity, together with finite element analysis (FEA). Results indicated that the pre-soaked micro-fiber mix (PMI) had maximum compressive strength (39 MPa), 18% more than control, while pre-soaked macro-fiber mix (PMA) had maximum flexural strength (3 MPa), 27.8% more than control. Durability tests also indicated PMA to reduce chloride diffusion by 44%, i.e., improved pore refinement. Dynamic modulus rose to 14%, confirming increased stiffness and fatigue life. FEA result confirmed trends with improved stress distribution and delayed failure in the pre-soaked fiber concretes. Pre-soaking basalt fibers guarantees overall improved fiber–matrix interfacial bond, internal curing, and sustainable response under Dynamic loading.
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Development and revalorization of the architectural heritage of Azerbaijan in the urban planning system

https://doi.org/10.58224/2618-7183-2026-9-4-9
Abstract
With a highly developed cultural heritage, Azerbaijan has always been known for its remarkable achievements in architecture and decorations. It serves as an optimal territory for the development of the modern approach to urban planning, supported by the governmental efforts to protect the values of this country at the level of world culture. Since gaining its independence, Azerbaijan has managed to develop a strong cooperation with UNESCO, making a great contribution to heritage conservation worldwide.
This paper studies the issue of the connection of the architectural legacy of Azerbaijan with the current system of urban development in theory and practice. Considering Baku as the key example of the discussed subject, the author analyses the successful co-existence of the historic structures in a developing city and tries to find out the ways to preserve the identity of this place during the process of the globalization of cities. Instead of working on restoration projects separately, the author suggests using the urban approach to preservation of the historic places as an important element of the socio-economic and architectural structure of the city. Moreover, the issue of the balance between the traditional aesthetics and modern constructions, along with the adaptive reuse of the historic areas is considered. There is a great focus made on the importance of international cooperation and compliance with the UNESCO requirements".
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Efficiency of applying various types of basic renewable energy sources in modern buildings and structures

https://doi.org/10.58224/2618-7183-2026-9-4-10
Abstract
The article presents a comprehensive analysis of the applicability and efficiency of basic renewable energy sources (RES) in modern buildings, including high-rise and unique structures. A comparative analysis of key technologies—solar (PV and thermal), wind, geothermal (heat pumps), and bioenergy—was conducted, highlighting their specific advantages as determined by efficiency indicators, COP, capacity factor (CUF), and temperature potential. The selection methodology is implemented as a sequence of iterative steps based on international statistical data (IRENA, IEA), modeling tools, and multi-criteria analysis principles. Key engineering requirements for the external and internal units of solar (photovoltaic and thermal), wind, geothermal systems, and bioenergy are identified. It is established that the selection and design of RES systems are determined by a triad of imperatives: achieving architectural harmony, maximizing energy efficiency, and ensuring safety and durability. A universal solution does not exist, and the efficiency of integration is determined by a combination of factors: climatic conditions, architectural and structural features of the building, and its energy profile. A typology of solutions for different building classes – from mass multi-story construction to skyscrapers – is proposed, with a detailed examination of wind and vibration loads, thermal deformations, and installation logistics. It is proven that for complex facilities, a hybrid approach is optimal, combining, in particular, geothermal heat pumps, building integrated photovoltaics (BIPV), and adapted small wind turbines. The article emphasizes the necessity of interdisciplinary design at the intersection of architecture, energy engineering, and mechanics to create efficient energy-active buildings. The transition from assessing RES potential in general to designing adaptive solutions for specific buildings is a necessary condition for creating energy efficient and carbon neutral buildings. The practical value of the work lies in providing designers and developers with a structured decision-making tool, which contributes to the creation of energy efficient, carbon neutral buildings and a sustainable urban environment.
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Rational technology for the use of glass cullet and fly ash in silicate bricks to improve the thermal insulation properties of enclosing structures

https://doi.org/10.58224/2618-7183-2026-9-3-1
Abstract
A topical issue in the modernization of housing and communal services is increasing the energy efficiency of enclosing structures while maintaining the standard strength and durability of wall materials. The study aimed to investigate opportunities for the use of glass cullet and fly ash in the production of autoclaved silicate bricks to reduce their thermal conductivity. The tested characteristics included average density, the thermal conductivity coefficient, compressive and flexural strength, water absorption, and frost resistance. The introduction of glass powder and fly ash was found to consistently lower the average density of silicate bricks from 1,910–1,950 to 1,625–1,700 kg/m³ and the thermal conductivity from 0.88–0.91 to 0.52–0.54 W/(m•K). The optimal compositions (samples No. 2 and No. 3) reduced thermal conductivity by 25–30% compared to the control sample with compressive strength remaining above 17.5 MPa and frost resistance in the range of F27–F35. An analysis of microstructural and phase characteristics based on SEM and XRD data showed that the improvement of thermophysical properties was due to the formation of a finely porous structure and a mixed hydrate matrix containing tobermorite and an amorphous C–S–H phase. The results confirm the expedience of using glass cullet and fly ash to produce energy-efficient silicate bricks suitable for use in enclosing structures in the framework of modernizing the facilities of housing and community services, which will not require major changes to current production technologies.
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Special features of obtaining a high-strength ceramic body based on modified argillites

https://doi.org/10.58224/2618-7183-2026-9-3-2
Abstract
After studying construction market trends over the past year, a rapid decline in ceramic materials production was revealed. According to Rosstat, construction materials output fell by 8.6% in September 2025 compared to the same month last year. Regarding the ceramic materials market, a decline was observed in the ceramic brick, stone, and tile production segment. Production of construction bricks decreased by 3.8%, ceramic stone by 4.8%, and ceramic facade tiles by 3.1%. Furthermore, clinker roofing tiles, large-format ceramic tiles, and siding are unavailable on the market, as imports of these products are limited and domestic production is nonexistent. Many ceramic material manufacturers are prepared to be modernized to support import substitution, thereby reducing the shortage in the construction industry. The primary challenge currently is to find raw materials suitable for the production of high-strength ceramic products. Argillites, which are widely distributed throughout the Russian Federation, could serve as such raw material. The main deposits of this raw material are located in the Southern and North Caucasian Federal Districts.
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Prospects for using bentonite-polymer composites to improve the strength and stability of iron ore pellets during granulation

https://doi.org/10.58224/2618-7183-2026-9-3-3
Abstract
The article investigates the application of bentonite-polymer composites (BPC) in the process of granulation of iron ore concentrates to increase the strength and stability of iron ore pellets. The purpose of the study was to optimize the physical and mechanical properties of the pellets using BPC as a binder. The relevance of the work is associated with the growing demand for more efficient pelletizing technologies capable of ensuring high-quality pellet production while reducing binder consumption and improving process stability. During the experiments, laboratory tests were performed with various dosages of bentonite and BPC, achieving a stabilized granulometric composition and improved strength characteristics of green pellets. The results showed that BPC added to the batch promoted a significant increase in compressive strength and a decrease in the abrasion of calcined pellets. In addition, binder consumption was found to be connected with the quality indicators of the product, enabling the optimization of the technological process and the achievement of target parameters. The paper stressed the importance of using high-quality binders to improve pellet efficiency and stability, which has significant implications for metallurgical production. Recommendations for the use of BPC can be applied in the development of new methods for the production of iron ore pellets with improved performance.
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Study of the aerodynamic characteristics and dispersed composition of halite salt dust

https://doi.org/10.58224/2618-7183-2026-9-3-4
Abstract
The paper presents the results of a comprehensive study of the physical and particle-size characteristics of halite salt dust, which is widely used in industry and traditionally not regarded as a hazardous environmental pollutant. Nevertheless, under large-scale production conditions, crushing, handling, storage, and transportation processes are accompanied by additional crystal fragmentation, which may lead to the formation of fine fractions and dust aerosols. Under certain aerodynamic conditions, such particles are capable of dispersing beyond industrial sites, thereby contributing to the problem of industrial air pollution. The aim of the study was to provide a quantitative assessment of the dust-forming tendency of halite salt and to determine the characteristics of the resulting dust fraction. The research included an analysis of the particle size (granulometric) distribution of both the initial material and the generated dust, experimental investigations of particle entrainment by airflow, determination of dust particle settling velocities, and measurement of their true density using the pycnometric method. The obtained data make it possible to assess the potential migration capacity of the fine fraction and its contribution to aerosol pollution under large-scale production conditions. It is shown that even with a relatively small mass fraction of fine particles, the total emission volumes may be significant due to high production capacities. The results of the study can be used in the development of dust suppression measures, optimization of technological regimes, improvement of dust collection systems, and in the environmental assessment of enterprises involved in the processing and storage of halite salt.
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A refined method for determining rheological parameters of the maxwell-gurevich equation from polymer relaxation curves using the example of epoxy resin edt-10

https://doi.org/10.58224/2618-7183-2026-9-3-5
Abstract
This paper presents a refined methodology for determining the rheological parameters of the nonlinear generalized Maxwell-Gurevich equation, which is widely used to describe creep and relaxation processes in polymer materials. Despite the extensive application of this constitutive model in polymer mechanics, existing methods for identifying its key parameters – namely the high-elasticity modulus E∞, the rate modulus mcr, and the initial relaxation viscosity ηcr,0 – often yield approximate values that do not fully capture the material's behavior across different deformation levels. The proposed approach addresses this limitation through a comprehensive two-stage algorithm based on the processing of stress relaxation curves at various initial strain levels. In the first stage, preliminary parameter values are obtained using an analytical approximation method that involves polynomial fitting of creep strain data and logarithmic transformation of the relaxation viscosity coefficient. The second stage employs numerical optimization techniques implemented in the Python programming language, specifically the scipy.optimize.fmin function for global minimum search, combined with the fourth-order Runge–Kutta method for solving the differential equation of creep strain rate. The methodology was validated using experimental data for EDT-10 epoxy resin – a thermosetting polymer widely employed in structural applications – tested at 20°C under six different initial relative deformations ranging from 0.008 to 0.035. The relaxation curves were digitized from classical literature sources and processed according to the developed algorithm. The results demonstrate that the rheological parameters of the Maxwell-Gurevich equation exhibit significant dependence on the initial strain (stress) level, contrary to the common assumption of their constancy for a given temperature. Specifically, the high-elasticity modulus E∞ decreases nonlinearly from 19142.71 MPa to 2643.07 MPa as the initial deformation increases, while the rate modulus mcr shows an increasing trend from 3.58 MPa to 22.48 MPa. The initial relaxation viscosity ηcr,0 decreases by approximately two orders of magnitude, from 8.14•10⁵ MPa•h to 1.33•10⁴ MPa•h. Functional relationships approximating these dependencies as functions of the initial elastic strain were established with high correlation coefficients (R² ranging from 0.9776 to 0.9988 for individual curves). A comparative analysis was conducted with three previously published parameter sets for EDT-10 epoxy resin. The comparison reveals that traditional constant-parameter approaches significantly underestimate the high-elasticity modulus and lead to excessively rapid stress relaxation, particularly at higher initial strain levels (>0.0155), where the solution degenerates. In contrast, the proposed strain-dependent parameterization yields theoretical relaxation curves that closely match the experimental data across the entire range of deformations, with coefficients of determination R² exceeding 0.97 for all curves except the lowest strain level (0.008), where digitization errors are more pronounced. The methodology demonstrates robustness and can be extended to other polymer materials and loading conditions, including creep tests where the stress remains constant. The findings have important implications for the mechanics of polymer structures, adhesive joints, and composite materials, where accurate prediction of long-term deformation behavior under various stress states is essential for reliable design and service life assessment. Future research directions include validation of the proposed hypothesis for creep curves and investigation of temperature-dependent parameter variations.
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Controlling the density and thermal conductivity of silicate bricks by adjusting the dispersity of glass powder from glass waste

https://doi.org/10.58224/2618-7183-2026-9-3-6
Abstract
Under tightening requirements for the energy efficiency of buildings, the development of building materials with reduced thermal conductivity and with the use of secondary resources is gaining particular relevance. A promising area is the use of cullet in the production technology of silicate bricks as a wall building material. The aim of the study was to investigate the influence of dispersity and the content of glass powder obtained from sheet glass waste on the physicomechanical and thermophysical properties of autoclaved silicate bricks. Glass powder was examined as an active silica-containing additive and a source of alkaline Na⁺ ions that affect hydrothermal phase formation. The samples were molded by semi-dry pressing at a pressure of 20 MPa and 10–12% humidity of the mixture, after which the bricks were autoclaved according to the industrial regime of the silicate brick factory of West Kazakhstan Corporation of Building Materials, JSC (174–175°C, 0.8 MPa). The introduction of 5–15% fine glass powder was found to decrease the average density and thermal conductivity coefficient of the product while maintaining strength at the level of grades M150–M200. Microstructural and phase analysis showed a predominance of an amorphous and semi-crystalline C–S–H phase with the suppression of tobermorite formation due to the alkaline effect of glass powder. The study determined that the modification of silicate bricks with glass powder allows obtaining more energy-efficient wall materials without changing the industrial production technology. The findings testify to the prospects of recycling cullet in the silicate brick production technology with the aims of increasing the energy efficiency of the enclosing structures.
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