Nizina T.A.

Doctor of Engineering Sciences (Advanced Doctor), Professor of Building Constructions Department, National Research Mordovia State University

Methodological aspects of training dataset construction for predicting the mechanical strength of filled polymer coatings during natural climatic aging

https://doi.org/10.58224/2618-7183-2026-9-4-3
Abstract
The paper presents the results of investigating the strength characteristics of eleven compositions of protective and decorative epoxy polymer coatings with mineral fillers and an unfilled polymer under natural climatic aging in a temperate climate (Saransk). The work formalises the methodological approach to the formation of a training dataset for predicting changes in the strength characteristics of polymer composites with mineral fillers using machine learning methods. It is shown that with the introduction of a mineral filler, the failure mode of the epoxy matrix under bending changes from viscous-fluid to brittle, which allows the bending strength to be unambiguously determined. Under uniaxial compression, the classical strength value is reached in the region of relative strains of 50 % and higher, which corresponds to the densification phase of the already failed material and does not physically reflect the actual strength response. As a methodologically correct alternative, the yield strength is proposed, identified as the first local maximum on the smoothed σ–ε curve and unambiguously determined for all studied compositions at all natural climatic aging points. The relative difference Δσ between the strength value (in bending) or the yield strength (in compression) of the filled composition and the corresponding stress value on the deformation curve of the unfilled polymer, taken at the same point of relative strains for each time point of climatic aging, is proposed as the target feature of the prediction model. This approach automatically eliminates from the target variable the components associated with the post-curing effects and the degradation of the polymer matrix itself, leaving the model with the task of predicting the contribution of the filler and the state of the polymer–filler interface. Based on the analysis of the reinforcing effect of the eleven filled compositions in the reference state without post-curing, three groups of fillers are identified according to the level of the relative strength gain under bending («low» 3÷10 %, «moderate» 24÷53 %, «high» 70÷120 %), which are consistent with the physical picture of the filler–polymer matrix interaction. Recommendations are formulated on the composition of the model's input feature space, including the type and shape of the filler particles, the mass fraction, the characteristic particle size, the specific surface area, and the characteristic relative strain of the composition in the reference state. It is noted that the bending tests possess substantially greater informativeness in the assessment of the climatic resistance of the investigated class of materials in comparison with uniaxial compression.
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Photocatalysts based on Zn-Ti layered double hydroxide and its calcination products for self-cleaning concretes: Structure formation and photocatalytic activity

https://doi.org/10.58224/2618-7183-2025-8-1-2
Abstract
Currently, the development of highly active photocatalytic additives for self-cleaning cement materials is a topical direction of building materials science. Mixed transition metal oxides are one of the effective types of photocatalysts, because they have improved functional characteristics compared to monometallic compounds. The purpose of this study was to establish the effects of synthesis conditions on the structure parameters and photocatalytic activity of zinc-titanium layered double hydroxide (Zn-Ti LDH) with Zn2+/Ti4+ molar ratio of 2/1, as well as its calcination products in the form of zinc-titanium mixed metal oxides (Zn-Ti MMOs). It was found that the mixing temperature of solutions of precursor salts and precipitators, as well as the temperature of sediment aging, were the main synthesis parameters that had the greatest impact on the phase composition and crystallite size of layered double hydroxide.
The research results showed differences in the kinetics of photodestruction of methylene blue (MB) in solution under UV radiation in the presence of Zn-Ti layered double hydroxide and Zn-Ti mixed metal oxides. The photocatalytic process involving Zn-Ti MMOs, corresponding to a pseudo-first order reaction kinetic, proceeded in a diffusion mode with limiting step in the form of dye adsorption on the surface of photocatalyst. The photodegradation of MB in the presence of Zn-Ti LDH, which was more accurately described by a pseudo-second order model, occurred in a kinetic regime, where the photocatalytic reaction was the limiting stage.
Mixed metal oxides of zinc and titanium had significantly higher functional characteristics compared to their Zn-Ti LDH precursor. The calcination of Zn-Ti layered double hydroxide at 200–500 °C allowed to achieve the highest photocatalytic activity of Zn-Ti MMO, which was due to phase transformations occurring during thermal treatment. The decomposition of Zn-Ti LDH at 200–250 °C resulted in the formation of a crystalline phase of zinc oxide (ZnO), which had a hexagonal wurtzite crystal structure with the ability to effectively absorb radiation from almost the entire UV spectral region. The rise of the Zn-Ti LDH calcination temperature to 500 °C led to an increase in the crystallinity degree of ZnO.
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