English
Русский 70-79 p.
The work is devoted to the investigation of the process of obtaining titanium oxide nanoparticles by burning high voltage DC gas discharge in an argon atmosphere when an aqueous solution is used as one of the electrodes. It was found that using an aqueous glycine solution in an inert gas medium, the plasma-electrolyte process using a streamer discharge is well suited for producing titanium oxide nanoparticles. An important regularity of particle size decrease with the increase of argon pressure in the chamber was revealed. Thus, when the pressure is increased from 1 MPa to 3 MPa, a sharp decrease in the average particle size from 62 nm to 16 nm is observed, while the changes in the aver-age particle size are not cardinal already in the process of pressure increase up to 5 MPa. A narrowing of the dispersion composition scatter with increasing pressure for 1 MPa - ± 40 nm, 3 MPa - ± 20 nm and 5 MPa - ± 8 nm was determined. The presence of titanium oxide particles was confirmed on the basis of plasmon resonance detection at 224, 230 and 235 nm.
[1] Szabolcs Fekete, Erzsébet Oláh, Jenő Fekete. Fast liquid chromatography: The domination of core–shell and very fine particles. Journal of Chromatography. 2012, 9 March. 1228. P. 57 – 71.
[2] Bao B, Wang Z., Thushara D., Liyanage A., Gunawardena S., Yang Z. et al. Recent advances in microfluidics-based chromatography – a mini review. Separations. 2021. 8. P. 3.
[3] Richar Hayes, Adham Ahmed, Tony Edge, Haifei Zhang. Core-shell particles: Preparation, fundamentals and applications in high performance liquid chromatography. Journal of Chromatography A. August 2014. 1357 (29). P. 36 – 52.
[4] Xiaojing Liang, Shujuan Liu, Shuai Wang, Yong Guo, Shengxiang Jiang. Carbon-based sorbents: Carbon nanotubes. Journal of Chromatography. 29 August 2014. 1357. P. 53 – 67.
[5] Bell DS. New liquid chromatography columns and accessories. LC.GC North America. 2019. 37. P. 232 – 243.
[6] Recent developments in LC column technology, Supplement to LC.GC North America 38. 2020. s6
[7] Pitchaimuthu S., Honda K., Suzuki S., Naito A., Suzuki N., Katsumata K., Nakata K., Ishida N., Kitamura N., Idemoto Y., Kondo T. Solution plasma process-derived defect-induced het-ero phase anatase/brookite TiO2 nanocrystals for enhanced gaseous photocatalytic perfor-mance. ACS Omega. 2018. 3. P. 898.
[8] Elashmawi I.S., Gaabour L., Raman H. Morphology and electrical behavior of nanocompo-sites based on PEO/PVDF with multi-walled carbon nanotubes. Results Phys. 2015. 5. P. 105.
[9] Kashapov L., Kashapov N., Kashapov R. Research of the impact acidity of electrolytic cath-ode on the course of the plasma-electrolytic process. Journal of Physics: Conference Series. 2013. 479 (1). P. 012011.
[10] Denisov D., Kashapov N., Kashapov R. The appearance of shock waves in the plasma elec-trolytic processing. IOP Conference Series: Materials Science and Engineering. ijun' 2015. 86 (1.26). P. 012005.
[11] Kashapov R., Kashapov N., Kashapov L. Investigations of the growth of the vapor-air shell of a gas discharge with a liquid electrolytic cathode of sodium hydroxide solution.Journal of Physics Conference Series. November 2017. 927 (1). P. 012085.
[12] Kashapov R., Kashapov N., Kashapov L. Research of plasma-electrolyte discharge in the processes of obtaining metallic powders. Journal of Physics Conference Series November. 2017. 927 (1). P. 012086.
[13] Kashapov N., Kashapov R., Kashapov L. Influence of the electrolytic cathode temperature on the self-sustaining mechanism of plasma-electrolyte discharge. Journal of Physics D Ap-plied Physics. September 2018. 51 (49).
[14] Kutukov A.K. Preparation of suspension of nanoscale and ultrafine powders of ZnO: Collec-tion of abstracts // III All-Russian competition of scientific reports of students “functional materials: development, research, application”, May 26-27, 2015, Tomsk, Tambov. (rus.)
[15] Tanabe I., Ozaki Y. Far- and deep-ultraviolet spectroscopic investigations for titanium diox-ide: electronic absorption, Rayleigh scattering, and Raman spectroscopy. J. Mater. Chem. 2016. 4. P. 7706.
[2] Bao B, Wang Z., Thushara D., Liyanage A., Gunawardena S., Yang Z. et al. Recent advances in microfluidics-based chromatography – a mini review. Separations. 2021. 8. P. 3.
[3] Richar Hayes, Adham Ahmed, Tony Edge, Haifei Zhang. Core-shell particles: Preparation, fundamentals and applications in high performance liquid chromatography. Journal of Chromatography A. August 2014. 1357 (29). P. 36 – 52.
[4] Xiaojing Liang, Shujuan Liu, Shuai Wang, Yong Guo, Shengxiang Jiang. Carbon-based sorbents: Carbon nanotubes. Journal of Chromatography. 29 August 2014. 1357. P. 53 – 67.
[5] Bell DS. New liquid chromatography columns and accessories. LC.GC North America. 2019. 37. P. 232 – 243.
[6] Recent developments in LC column technology, Supplement to LC.GC North America 38. 2020. s6
[7] Pitchaimuthu S., Honda K., Suzuki S., Naito A., Suzuki N., Katsumata K., Nakata K., Ishida N., Kitamura N., Idemoto Y., Kondo T. Solution plasma process-derived defect-induced het-ero phase anatase/brookite TiO2 nanocrystals for enhanced gaseous photocatalytic perfor-mance. ACS Omega. 2018. 3. P. 898.
[8] Elashmawi I.S., Gaabour L., Raman H. Morphology and electrical behavior of nanocompo-sites based on PEO/PVDF with multi-walled carbon nanotubes. Results Phys. 2015. 5. P. 105.
[9] Kashapov L., Kashapov N., Kashapov R. Research of the impact acidity of electrolytic cath-ode on the course of the plasma-electrolytic process. Journal of Physics: Conference Series. 2013. 479 (1). P. 012011.
[10] Denisov D., Kashapov N., Kashapov R. The appearance of shock waves in the plasma elec-trolytic processing. IOP Conference Series: Materials Science and Engineering. ijun' 2015. 86 (1.26). P. 012005.
[11] Kashapov R., Kashapov N., Kashapov L. Investigations of the growth of the vapor-air shell of a gas discharge with a liquid electrolytic cathode of sodium hydroxide solution.Journal of Physics Conference Series. November 2017. 927 (1). P. 012085.
[12] Kashapov R., Kashapov N., Kashapov L. Research of plasma-electrolyte discharge in the processes of obtaining metallic powders. Journal of Physics Conference Series November. 2017. 927 (1). P. 012086.
[13] Kashapov N., Kashapov R., Kashapov L. Influence of the electrolytic cathode temperature on the self-sustaining mechanism of plasma-electrolyte discharge. Journal of Physics D Ap-plied Physics. September 2018. 51 (49).
[14] Kutukov A.K. Preparation of suspension of nanoscale and ultrafine powders of ZnO: Collec-tion of abstracts // III All-Russian competition of scientific reports of students “functional materials: development, research, application”, May 26-27, 2015, Tomsk, Tambov. (rus.)
[15] Tanabe I., Ozaki Y. Far- and deep-ultraviolet spectroscopic investigations for titanium diox-ide: electronic absorption, Rayleigh scattering, and Raman spectroscopy. J. Mater. Chem. 2016. 4. P. 7706.
Kashapov R.N., Kashapov N.F., Kashapov L.N., Klyuev S.V., Chebakova V.Yu. Study of the plasma-electrolyte process for producing titanium oxide nanoparticles. Construction Materials and Products. 2022. 5 (5). P. 70 – 79. https://doi.org/10.58224/2618-7183-2022-5-5-70-79