Alfimova N.I.

Candidate of Engineering Sciences (Ph.D.), Associate Professor, Belgorod State Technological University named after V.G. Shukhov, Russia

Involvement of concrete internal potential to reduce portland cement consumption and ensure sustainable development

https://doi.org/10.58224/2618-7183-2025-8-5-9
Abstract
Protection of artificial human habitat from negative impacts of external environment and extension of service life of building structures become priority tasks of structural concrete improvement. The most important vector of development is the increase of their strength due to involvement of the internal resources with minimal use of additional external ones, which corresponds to the sustainable development concept. However, practice shows that now application of high-strength concretes, which are the main focus of researchers, is very limited due to insufficient development of production infrastructure, regulatory documentation, design and construction methods, economic and other reasons.
At the same time, approximation to requirements, according to the sustainable development concept, for the most widely used concretes with grade strength classes (B20-B50) is required right now. In this regard, the idea of application of the most important principles of obtaining high-strength self-compacting concretes in the manufacture of medium strength material is relevant. The article presents the main stages of research on development of the design methodology of medium strength classes self-compacting concretes with reduced Portland cement consumption.
The methodological basis for designing these concretes is the successive introduction of additional components principle while recording their effect on the material properties. The use of ground quartz sand as a mineral additive is due to the concrete mix stability requirements and its widespread availability, which allows for the practical application of the obtained results with minimal barriers and contributes to the reduction of CO2 emissions. It has been established that when selecting sand fineness of 180...220 m2/kg and a fixed amount of active mineral additive (7.5%), the compressive strength of the cement paste can be reduced to the following linear dependence: Rbinder28 = 118.9 – 0.22CM. Rational contents of fine and coarse aggregates have been identified, and their quantitative effect on the strength of the resulting concrete has been established. It has been established that the obtained concretes with increased efficiency of Portland cement using can be used in practice in various construction areas, and are also necessary for the search and transparent monitoring of the influence of others, more reactive mineral additives based on industrial products and rocks.
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EFFECT OF THE CURING CONDITIONS ON THE CHARACTERISTICS OF CITROGYPSUM-CONTAINING ALKALI-ACTIVATED BINDERS

https://doi.org/10.34031/2618-7183-2021-4-5-24-34
Abstract
When hardening the binder system and it transforms into a consolidated conglomerate, the efficiency of the formation of the structural framework and the main operational characteristics of the final product dramati-cally depend on the thermal and humidity conditions of the environment medium, where the binder or raw material is consolidated. In this study, various conditions of hardening of binders with alkaline activation of various compositions were studied. Based on the literature analysis, the following were chosen as the hardening conditions for the experimental alkali-activated systems: 1) - thermal drying, which was carried out in an oven at a temperature of 60°C for 24 hours; 2) hardening in ambient laboratory conditions, at a temperature of 23 ± 2°С, relative humidity - 33 ± 2%. An aqueous solution of alkali NaOH and salt Na2SiO3 were used as alkaline activators. The resulted data of the change in the average density showed that when using an alkaline activator, heat drying promotes the compaction of the hardened composite (typical for both types of the alkaline component) by 5 and 7 % for NaOH and Na2SiO3, respectively. The absence of alkaline activators in the experimental samples leads to decompaction of the structure after exposure to thermal drying and a decrease in the average density to 18%. The experimental results showed that thermal drying contributes to an increase in the strength parameters of experimental samples of an alkali-activated binder using Na2SiO3 to 110% (from 1.9 to 4 MPa). For the rest of the samples, a significant decrease in strength is observed (more than 2 times). A visual analysis of experimental samples of alkali-activated binders showed that the binders containing the addition of citrogypsum showed clear signs of efflorescence in the case of their hardening in ambient laboratory conditions. At the same time, for similar compositions from a series of samples hardened under thermal drying conditions, there is a complete absence of this phenomenon.
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UTILIZATION OF GYPSUM-BEARING WASTES IN MATERIALS OF THE CONSTRUCTION INDUSTRY AND OTHER AREAS

https://doi.org/10.34031/2618-7183-2021-4-1-5-17
Abstract
Rational environmental management is one of the priorities of the technological development of the Russian Federation and most countries of the world. Particularly important in this area is the work undertaken with previously generated and accumulated waste, a whole group of which is gypsum-bearing wastes (GBW), which includes by-products of various industries: phosphogypsum, borogypsum, chlorogypsum, ferrogypsum, citrogypsum, vitamin gypsum, etc. GBW features are similar compositions, prevalence, perennial volumes of stored reserves with stable dynamics of annual growth. This determines the relevance of research on the development of a unified methodology for converting GBW of various types into target products particularly for construction purposes, providing maximum energy efficiency and minimal generation of secondary waste. The starting point of the research is the monitoring of approaches developed by the scientific community which are presented in the article. It is shown that researchers are exploring several main areas of GBW conversion: components of Portland cement and clinker; single and multicomponent binders; direct raw materials for the production of building materials; and road construction. The latter two directions have the greatest potential capacity for the consumption of GBW. The general level of research on the issue is not exhaustive, but has the potential to improve on existing methods of processing and application and promote the search for new and more efficient methods.
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